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230502

Sigma-Aldrich

溴化亚铜与二甲基硫的络合物

99%

同義詞:

溴化亚铜与甲基硫的络合物, 溴化亚铜二甲基硫化物复合物, 溴化亚铜甲基硫化物

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About This Item

線性公式:
CuBr · CH3SCH3
CAS號碼:
分子量::
205.58
Beilstein:
4386581
EC號碼:
MDL號碼:
分類程式碼代碼:
12161600
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

99%

形狀

solid

反應適用性

core: copper
reagent type: catalyst

mp

132 °C (dec.) (lit.)

SMILES 字串

[Cu]Br.CSC

InChI

1S/C2H6S.BrH.Cu/c1-3-2;;/h1-2H3;1H;/q;;+1/p-1

InChI 密鑰

PMHQVHHXPFUNSP-UHFFFAOYSA-M

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相關類別

應用

用于格氏试剂(烷基、烯基、芳基)加成为富勒烯的催化剂。该反应对 [60]富勒烯添加 5 个有机基团,对 [70]富勒烯添加 3 个基团。

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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分析證明 (COA)

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Organic Syntheses, 83, 80-80 (2006)
Beatriz Pacheco Berciano et al.
Organic letters, 12(18), 4038-4041 (2010-08-26)
The copper-catalyzed direct alkynylation of azoles with 1,1-dibromo-1-alkenes as electrophiles is described. These easily accessible substrates are a useful addition to the field of direct alkynylations in an efficient and functional group tolerant reaction to provide a straightforward entry to
Enantioselective Cu-catalyzed 1,4-addition of Grignard reagents to cyclohexenone using taddol-derived phosphine-phosphite ligands and 2-methyl-THF as a solvent.
Tobias Robert et al.
Angewandte Chemie (International ed. in English), 47(40), 7718-7721 (2008-09-06)
Rossiter, B. E. et al.B. E.; Swingle, N. M.
Chemical Reviews, 92, 771-771 (1992)

文章

Reagents for C–C Bond Formation

We carry a large variety of electrophiles and nucleophiles that are widely used in C–C bond-forming reactions. This group of products contains many organometallic reagents as well as commonly-used alkylating and acylating reagents.

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