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Key Documents

283673

Sigma-Aldrich

三氟甲磺酸铜 (II)

98%

同義詞:

Cu(OTf)2, 三氟甲烷磺酸铜, 三氟甲磺酸 铜(II) 盐, 三氟甲磺酸铜

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About This Item

線性公式:
(CF3SO3)2Cu
CAS號碼:
分子量::
361.68
Beilstein:
4028198
EC號碼:
MDL號碼:
分類程式碼代碼:
12161600
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

98%

反應適用性

core: copper
reagent type: catalyst

mp

≥300 °C

SMILES 字串

FC(F)(F)S(=O)(=O)O[Cu]OS(=O)(=O)C(F)(F)F

InChI

1S/2CHF3O3S.Cu/c2*2-1(3,4)8(5,6)7;/h2*(H,5,6,7);/q;;+2/p-2

InChI 密鑰

SBTSVTLGWRLWOD-UHFFFAOYSA-L

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相關類別

應用

可用作以下反应的催化剂:
  • 曼尼希缩合反应
  • 环状氨基化
  • Friedel-Crafts反应
  • Henry反应
  • 高价碘试剂介导的咔唑制备
  • 分子内氧化C-N键形成以合成咔唑
有效催化三甲基氰硅烷加成为羰基化合物。

相關產品

產品號碼
描述
訂價

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Ahmed M Senan et al.
Journal of agricultural and food chemistry, 65(32), 6912-6918 (2017-07-19)
Utilization of renewable biomass to partly replace the fossil resources in industrial applications has attracted attention due to the limited fossil feedstock with the increased environmental concerns. This work introduced a modified Wacker-type oxidation for transformation of unsaturated fatty acids/esters
Saravanan, P. et al.
Tetrahedron Letters, 39, 3823-3823 (1998)
Dario Formenti et al.
Chemical reviews, 119(4), 2611-2680 (2018-12-06)
The reduction of nitro compounds to the corresponding amines is one of the most utilized catalytic processes in the fine and bulk chemical industry. The latest development of catalysts with cheap metals like Fe, Co, Ni, and Cu has led
Nicole W G Smits et al.
Inorganic chemistry, 58(19), 13007-13019 (2019-09-25)
The structure of the copper complex of the 6-((1-butanethiol)oxy)-tris(2-pyridylmethyl)amine ligand (Cu-tmpa-O(CH2)4SH) anchored to a gold surface has been investigated. To enable covalent attachment of the complex to the gold surface, a heteromolecular self-assembled monolayer (SAM) of butanethiol and a thiol-substituted
Juan Ramírez et al.
Inorganic chemistry, 48(6), 2456-2463 (2009-03-10)
A novel class of ditopic ligands, 1, was synthesized by the reaction of 2,5-pyrazine-dicarboxaldehyde with 2 equiv of acyl-/aroyl-hydrazine. Their structures were confirmed by 1D and 2D NMR and by X-ray crystallography. They gave heteroleptic Cu(II) dinuclear rack-like complexes of

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