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407240

Sigma-Aldrich

三氟甲烷磺酸铜与苯的络合物

technical grade, 90%

同義詞:

三氟甲烷磺酸铜盐苯络合物, 三氟甲烷磺酸铜苯络合物, 三氟甲磺酸铜苯络合物

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About This Item

線性公式:
(CF3SO3Cu)2 · C6H6
CAS號碼:
分子量::
503.34
EC號碼:
MDL號碼:
分類程式碼代碼:
12161600
PubChem物質ID:
NACRES:
NA.22

等級

technical grade

品質等級

化驗

90%

形狀

powder

反應適用性

core: copper
reagent type: catalyst

mp

160 °C (dec.) (lit.)

SMILES 字串

[Cu+].[Cu+].c1ccccc1.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F

InChI

1S/C6H6.2CHF3O3S.2Cu/c1-2-4-6-5-3-1;2*2-1(3,4)8(5,6)7;;/h1-6H;2*(H,5,6,7);;/q;;;2*+1/p-2

InChI 密鑰

GNXZWVVAAMVOJY-UHFFFAOYSA-L

應用

三氟甲磺酸铜(I)苯络合物可用作以下反应的催化剂:
  • 通过形成羧酸铜(I)中间体,合成烯醇酯。
  • 环状烯烃的对映选择性烯丙基氧化。
  • 通过形成磺酰胺基自由基,由N-烯基、炔基和烷基N-苯甲酰氧基磺酰胺制备2,5-二取代的吡咯烷衍生物。

它还可与基于氨基酸的手性膦配体结合使用,催化烷基锌与无环α,β-不饱和酮的不对称共轭加成,以高产率和优异的对映选择性合成β-烷基羰基。

象形圖

Flame

訊號詞

Warning

危險聲明

危險分類

Flam. Sol. 2

儲存類別代碼

4.1B - Flammable solid hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Jerome Bayardon et al.
The Journal of organic chemistry, 69(9), 3121-3128 (2004-04-24)
Various enantiopure fluorous bis(oxazolines) with fluorine content between 52.7 and 58.7% have been synthesized by a simple reaction sequence that involved the introduction of two fluorinated ponytails by alkylation of the corresponding nonfluorous bis(oxazolines). These new ligands have been used
Enantioselective total synthesis of erogorgiaene: applications of asymmetric Cu-catalyzed conjugate additions of alkylzincs to acyclic enones
Cesati RR, et al.
Journal of the American Chemical Society, 126(1), 96-101 (2004)
Synthesis of Enol Esters from Copper (I) Carboxylates Generated from Copper (I) Trifluoromethanesulfonate Benzene Complex
Lefler SR and Rose SD
Synthetic Communications, 29(21), 3805-3810 (1999)
Richard R Cesati et al.
Journal of the American Chemical Society, 126(1), 96-101 (2004-01-08)
The first enantioselective synthesis of erogorgiaene (1), an inhibitor of mycobacterium tuberculosis, is disclosed. The total synthesis highlights the utility of asymmetric conjugate additions (ACA) of alkylzincs to acyclic alpha,beta-unsaturated ketones catalyzed by peptidic phosphine ligands and (CuOTf)(2).C(6)H(6). Moreover, several
Enantiopure fluorous bis (oxazolines): Synthesis and applications in catalytic asymmetric reactions
Bayardon J and Sinou D
The Journal of Organic Chemistry, 69(9), 3121-3128 (2004)

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