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重要文件

175501

Sigma-Aldrich

三氟化硼二乙醚

for synthesis

同義詞:

三氟化硼乙醚

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About This Item

線性公式:
BF3 · O(C2H5)2
CAS號碼:
分子量::
141.93
Beilstein:
3909607
EC號碼:
MDL號碼:
分類程式碼代碼:
12352106
PubChem物質ID:
NACRES:
NA.22

等級

for synthesis
synthesis grade

品質等級

蒸汽密度

4.9 (vs air)

蒸汽壓力

4.2 mmHg ( 20 °C)

形狀

liquid

expl. lim.

36 %

反應適用性

core: boron
reagent type: Lewis acid
reagent type: catalyst

折射率

n20/D 1.344 (lit.)

bp

126-129 °C (lit.)

mp

−58 °C (lit.)

密度

1.15 g/mL (lit.)

官能基

ether

儲存溫度

2-8°C

SMILES 字串

CC[O+](CC)[B-](F)(F)F

InChI

1S/C4H10BF3O/c1-3-9(4-2)5(6,7)8/h3-4H2,1-2H3

InChI 密鑰

MZTVMRUDEFSYGQ-UHFFFAOYSA-N

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相關類別

一般說明

三氟化硼乙醚或三氟化硼乙醚络合物是一种有机化合物,被广泛用作有机合成中便捷的三氟化硼(BF3)源。它也可用作活化亲电子试剂的路易斯酸。

應用

具有广泛用途的路易斯酸试剂
由芳基环丙酮通过 [3+2] 环加成反应制备环戊基和环庚基[b]吲哚的催化剂。

包裝

建议将25 mL Sure/Seal 瓶作为一次性瓶使用。 反复穿刺可能会导致产品性能下降。

法律資訊

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

相關產品

產品號碼
描述
訂價

訊號詞

Danger

危險分類

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT RE 1 Inhalation

標靶器官

Kidney

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 1

閃點(°F)

137.3 °F - closed cup

閃點(°C)

58.5 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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存取文件庫

European Journal of Organic Chemistry, 5378-5378 (2006)
Meng-Yang Chang et al.
Organic letters, 12(6), 1176-1179 (2010-03-03)
An easy and straightforward synthesis of 6,10b-diarylhexahydrobenzo[f]isoquinoline by the repeated treatment of boron trifluoride etherate (BF(3) x OEt(2)) is reported. The overall transformation from 4-arylpiperidin-3-one to benzo[f]isoquinoline proceeds via ring contraction, chain elongation, and intramolecular electrophilic cyclization in moderate yields.
(1-Alkynyl)dicarbonylcyclopentadienyliron complexes as electron-rich alkynes in organic synthesis: BF3-mediated [2+2] cycloaddition/ring-opening providing (2-alkenyl-1-imino)iron complexes.
Ryotaro Nakaya et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 17(31), 8559-8561 (2011-06-23)
Kevin M McQuaid et al.
Journal of the American Chemical Society, 131(2), 402-403 (2008-12-23)
C-H bond functionalization enables strategically new approaches to the synthesis of complex organic molecules including biologically active compounds, research probes and functional organic materials. To address the shortcomings of transition metal catalyzed processes, we have developed a new approach to
U C Reddy et al.
The Journal of organic chemistry, 74(6), 2605-2608 (2009-02-17)
A diastereoselective one-pot, three-component Prins-Friedel-Crafts reaction was developed for the synthesis of 4-aryltetrahydropyran derivatives from the reaction of carbonyl compounds with homoallylic alcohol in the presence of arene promoted by boron trifluoride etherate.

Global Trade Item Number

庫存單位GTIN
175501-4L4061838252159
175501-4X25ML4061838252166
175501-5ML4061838752321
175501-100ML4061838752314
175501-1L4061838252142

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