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222380

Sigma-Aldrich

氯化烯丙基钯(II)二聚体

greener alternative

98%

同義詞:

双((η3-烯丙基)(氯)钯), 二-ο-烯丙基二-μ-氯二钯, \ [氯化钯(C3H5)] 2

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About This Item

經驗公式(希爾表示法):
C6H10Cl2Pd2
CAS號碼:
分子量::
365.89
Beilstein:
4124623
EC號碼:
MDL號碼:
分類程式碼代碼:
12161600
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

98%

形狀

solid

反應適用性

core: palladium
reaction type: Cross Couplings
reagent type: catalyst
reaction type: C-H Activation

環保替代產品特色

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

環保替代類別

儲存溫度

2-8°C

SMILES 字串

Cl[Pd]CC=C.Cl[Pd]CC=C

InChI

1S/2C3H5.2ClH.2Pd/c2*1-3-2;;;;/h2*3H,1-2H2;2*1H;;/q;;;;2*+1/p-2

InChI 密鑰

TWKVUTXHANJYGH-UHFFFAOYSA-L

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一般說明

我们致力于为您提供更环保的替代产品,以符合“绿色化学的12项原则”的一项或多项原则要求。该产品为增强型,提高了催化效率。 点击此处以获取更多信息。
氯化烯丙基钯二聚体被用作Heck反应的催化剂。它还作为催化剂参与炔醛与烯丙基氯和烯丙基丁基锡烷的串联亲核烯丙基化-烷氧基烯丙基化反应。

應用

烯丙基钯(II)氯化物二聚体已用于以下研究:
  • 微波辅助Heck芳基化用阳离子钯催化剂的合成。
  • N-杂环卡宾-钯-η3-烯丙基氯络合物的合成:它是芳基溴化物和活化芳基氯化物Suzuki-Miyaura交叉偶联的有效催化剂。
  • 1,4-二烯丙基-1,2-二氢异喹啉的合成。
  • 作为TPGS-750-M更绿色Buchwald-Hartwig耦合的催化剂

朝着通过E因子而量化的绿色过渡金属催化过程前进

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Skin Irrit. 2

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

個人防護裝備

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


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分析證明 (COA)

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存取文件庫

An N-heterocyclic carbene-palladium-η3-allyl chloride complex for the Suzuki-Miyaura coupling of aryl halides.
Broekemier NW, et al.
European Journal of Chemistry, 5(1), 162-166 (2014)
Radetich, B.; RajanBabu, T. V.
Journal of the American Chemical Society, 120, 8007-8007 (1998)
Yasuyuki Harada et al.
Organic letters, 7(20), 4385-4387 (2005-09-24)
[reaction: see text] The reaction of yne esters with carbon monoxide (1 atm) in the presence of palladium complexes gives bicyclic unsaturated lactone derivatives in good to high yields. The 2-pyridinyloxy group is a good leaving group among leaving groups
Superhydrophobicity of nanostructured carbon films in a wide range of pH values.
Lin Feng et al.
Angewandte Chemie (International ed. in English), 42(35), 4217-4220 (2003-09-23)
Tandem nucleophilic allylation-alkoxyallylation of alkynylaldehydes via amphiphilic bis-p-allylpalladium complexes.
Nakamura H, et al.
Tetrahedron Letters, 43(42), 7631-7633 (2002)

文章

TPGS-750-M, a second generation surfactant, is useful for room temperature, palladium and ruthenium-catalyzed reactions in water. Reactions include the Heck reaction, Suzuki-Miyaura reaction, Sonogashira reaction, Buchwald-Hartwig amination reaction, Negishi reaction, and olefin metathesis.

TPGS-750-M, a second generation surfactant, is useful for room temperature, palladium and ruthenium-catalyzed reactions in water. Reactions include the Heck reaction, Suzuki-Miyaura reaction, Sonogashira reaction, Buchwald-Hartwig amination reaction, Negishi reaction, and olefin metathesis.

The Heck reaction is the palladium catalyzed cross-coupling reaction between alkenes and aryl or vinyl halides (or triflates) to afford substituted alkenes.

The Heck reaction is the palladium catalyzed cross-coupling reaction between alkenes and aryl or vinyl halides (or triflates) to afford substituted alkenes.

條款

Buchwald-Hartwig Amination Reaction in Water at Room Temperature using TPGS-750-M

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