推薦產品
形狀
liquid
品質等級
反應適用性
reagent type: reductant
濃度
1.0 M in toluene
密度
0.858 g/mL at 25 °C
SMILES 字串
CC(C)C[AlH]CC(C)C
InChI
1S/2C4H9.Al.H/c2*1-4(2)3;;/h2*4H,1H2,2-3H3;;
InChI 密鑰
AZWXAPCAJCYGIA-UHFFFAOYSA-N
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應用
二异丁基氢化铝溶液(1M,溶剂为甲苯)已被用于将氮丙啶酯还原成相应的醛。 它还用于从醇合成二烷基铝醇盐。
用于Pd催化的仲烷基溴的还原脱溴过程。过苄基化呋喃糖苷的O-脱苄基和开环。方便从 ZrCp2Cl2 和DIBAL-H原位生成 HZrCp2Cl。
法律資訊
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
訊號詞
Danger
危險分類
Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1B - STOT RE 2 Inhalation - STOT SE 3 - Water-react 1
標靶器官
Central nervous system
安全危害
儲存類別代碼
4.2 - Pyrophoric and self-heating hazardous materials
水污染物質分類(WGK)
WGK 3
閃點(°F)
39.2 °F - closed cup
閃點(°C)
4 °C - closed cup
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An optimized protocol for the DIBALH reductive acetylation of acyclic esters and diesters is described. This reductive acetylation procedure allows a wide variety of esters to be converted into the corresponding alpha-acetoxy ethers in good to excellent yields. It was
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