推薦產品
形狀
liquid
品質等級
反應適用性
reagent type: reductant
濃度
1.0 M in THF
bp
65 °C
密度
0.866 g/mL at 25 °C
儲存溫度
2-8°C
SMILES 字串
CC(C)C[AlH]CC(C)C
InChI
1S/2C4H9.Al.H/c2*1-4(2)3;;/h2*4H,1H2,2-3H3;;
InChI 密鑰
AZWXAPCAJCYGIA-UHFFFAOYSA-N
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應用
二异丁基氢化铝溶液（1M；溶于THF中）是一种强力还原剂。它可用于以下反应：
- 合成经二肽保护的 反式-烯烃同构物。
- 原位生成双（1,5-环辛二烯）镍（0）（Ni（cod）2），其可催化将 乙烯基三丁基锡共轭加成至 2-丙烯醛，以形成 叔丁基二甲基[（（E）-1,4-戊二烯基）氧基]硅烷。
- 还原芳基丙酸酯，以得到相应的炔丙醇。
用于Pd催化的仲烷基溴的还原脱溴过程。过苄基化呋喃糖苷的O-脱苄基和开环。方便从 ZrCp2Cl2 和DIBAL-H原位生成 HZrCp2Cl。
包裝
查看可回收的容器产品。
訊號詞
Danger
危險分類
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Skin Corr. 1B - STOT SE 3 - Water-react 1
標靶器官
Central nervous system, Respiratory system
安全危害
儲存類別代碼
4.2 - Pyrophoric and self-heating hazardous materials
水污染物質分類（WGK）
WGK 1
閃點（°F）
1.4 °F - closed cup
閃點（°C）
-17 °C - closed cup
個人防護裝備
Faceshields, Gloves, Goggles
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A continuous flow system for the multiparameter (flow rate, temperature, residence time, stoichiometry) optimization of the DIBALH reduction of esters to aldehydes is described. Incorporating an in-line quench (MeOH), these transformations are generally complete in fewer than 60 s. Mixing
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D J Kopecky et al.
The Journal of organic chemistry, 65(1), 191-198 (2000-05-18)
An optimized protocol for the DIBALH reductive acetylation of acyclic esters and diesters is described. This reductive acetylation procedure allows a wide variety of esters to be converted into the corresponding alpha-acetoxy ethers in good to excellent yields. It was
J Marco-Contelles et al.
Carbohydrate research, 335(1), 63-70 (2001-09-13)
The reaction of DIBALH with bis(heteroannulated)-pyranosides containing the perhydrofuro[2,3-b]pyran moiety is described. The hydride attack at the anomeric carbon (C-9a) resulted in the exclusive tetrahydrofuran ring opening. The selectivity of this reaction has been evaluated as other benzylidene acetals built
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