ALD00617

(−)-PI Reagent

≥95%

• 别名: (2R,3aS,5R,7aS)-7a-Methyl-2-((perfluorophenyl)thio)-5-(prop-1-en-2-yl)hexahydrobenzo[d][1,3,2]oxathiaphosphole 2-sulfide, Phosphorus Incorporation reagent
• 经验公式（希尔记法）: C₁₆H₁₆F₅OPS₃
• CAS号: 2269472-45-7
• 分子量: 446.46
• MDL號碼: MFCD34549926
• 分類程式碼代碼: 12352005
• NACRES: NA.22

属性

• 品質等級: 100
• 化驗: ≥95%
• 形狀: powder
• mp: 118-123 °C
• SMILES 字串: Fc1c(c(c(c(c1F)F)S[P]2(=S)S[C@@H]3[C@@](O2)(CC[C@H](C3)C(=C)C)C)F)F
• InChI: 1S/C16H16F5OPS3/c1-7(2)8-4-5-16(3)9(6-8)25-23(24,22-16)26-15-13(20)11(18)10(17)12(19)14(15)21/h8-9H,1,4-6H2,2-3H3/t8-,9+,16+,23?/m1/s1
• InChI 密鑰: CZCFCQOKUBIPHN-QSHUGKRNSA-N

说明

應用

(−)-PI Reagent is an air- and moisture-tolerant, reagent developed in the Baran lab for stereospecific synthesis of chiral phosphines and methylphosphonate nucleotides. The enantiomer, (+)-PI Reagent, is also available.

Learn more about PI and PSI reagents

其他說明

Enantiodivergent formation of C-P bonds: synthesis of P-chiral phosphines and methyl-phosphonate oligonucleotides

安全信息

• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable