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225754

Sigma-Aldrich

烯丙基溴化镁 溶液

1.0 M in diethyl ether

别名:

(Prop-2-en-1-yl)magnesium bromide, 2-Propenylmagnesium bromide, Allyl magnesium bromide, Allylbromomagnesium, Allylmagnesiumbromide, Bromo-2-propenylmagnesium

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About This Item

线性分子式:
CH2=CHCH2MgBr
CAS号:
1730-25-2
分子量:
145.28
Beilstein:
969335
MDL號碼:
MFCD00000044
分類程式碼代碼:
12352103
PubChem物質ID:
24853518
NACRES:
NA.22

品質等級

100

反應適用性

reaction type: Grignard Reaction

濃度

1.0 M in diethyl ether

密度

0.851 g/mL at 25 °C

SMILES 字串

Br[Mg]CC=C

InChI

1S/C3H5.BrH.Mg/c1-3-2;;/h3H,1-2H2;1H;/q;;+1/p-1

InChI 密鑰

FEMBXICCJNZMMC-UHFFFAOYSA-M

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一般說明

烯丙基溴化镁溶液可用作氮杂-芳香杂环（aza-aromatic heterocycle）的选择性亲核试剂。

應用

烯丙基溴化镁溶液可用于格氏反应，这是合成的关键步骤：
  • 2-（9，10-二氢-9，10-丙酰基-9-基）-N-甲基乙胺（2），苯并喋呤的同系物
  • tarchonanthuslactone
  • （+）-preussin
  • 多羟基化喹嗪类生物碱

包裝

查看可回收的容器产品。

訊號詞

Danger

危險分類

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 1 - Skin Corr. 1B - STOT SE 3 - Water-react 1

標靶器官

Central nervous system

安全危害

EUH019

儲存類別代碼

4.3 - Hazardous materials which set free flammable gases upon contact with water

水污染物質分類（WGK）

WGK 1

閃點（°F）

-40.0 °F - closed cup

閃點（°C）

-40 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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分析证书(COA)

Lot/Batch Number
SHBM1555
SHBJ6101
SHBH8690
SHBG9257V
SHBG3220V

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访问文档库

An Efficient Asymmetric Synthesis of Tarchonanthuslactone1.
Reddy M, et al.
The Journal of Organic Chemistry, 66(7), 2512-2514 (2001)
Stereoselective synthesis of the antifungal antibiotic (+)-preussin.
Veeresa G, et al.
Tetrahedron, 54(51), 15673-15678 (1998)
Synthesis of 2-(9, 10-dihydro-9, 10-propanoanthracen-9-yl)-N-methylethanamine via a [4+ 2] cycloaddition.
Karama U, et al.
Molecules (Basel), 15(6), 4201-4206 (2010)
Synthesis of trihydroxy quinolizidine alkaloids: 1, 3-addition reaction of allylmagnesium bromide to a sugar nitrone.
Dhavale DD, et al.
Tetrahedron, 60(13), 3009-3016 (2004)

商品

Reagents for C–C Bond Formation

We carry a large variety of electrophiles and nucleophiles that are widely used in C–C bond-forming reactions. This group of products contains many organometallic reagents as well as commonly-used alkylating and acylating reagents.

Reagents for C–C Bond Formation

We carry a large variety of electrophiles and nucleophiles that are widely used in C–C bond-forming reactions. This group of products contains many organometallic reagents as well as commonly-used alkylating and acylating reagents.

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