推荐产品
等級
reagent grade
品質等級
蒸汽密度
4.2 (vs air)
化驗
97%
形狀
liquid
自燃溫度
554 °F
包含
≤1000 ppm propylene oxide as stabilizer
expl. lim.
7.3 %
折射率
n20/D 1.469 (lit.)
bp
70-71 °C (lit.)
mp
−119 °C (lit.)
密度
1.398 g/mL at 25 °C (lit.)
官能基
alkyl halide
bromo
儲存溫度
2-8°C
SMILES 字串
BrCC=C
InChI
1S/C3H5Br/c1-2-3-4/h2H,1,3H2
InChI 密鑰
BHELZAPQIKSEDF-UHFFFAOYSA-N
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應用
使用烯丙基溴:
- 通过Suzuki型偶联反应合成立体定向烯丙基化芳烃。
- 应用于醛和酮的Barbier型烯丙基反应。{17]
- 合成一个单体,1-1-(烯丙氧基)-4-硝基苯,同时合成纳米结构分子印迹聚合物,用于在生物和药物样品中选择性色氨酸的测定。
訊號詞
Danger
危險分類
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 2 - Muta. 1B - Skin Corr. 1B
儲存類別代碼
3 - Flammable liquids
水污染物質分類(WGK)
WGK 3
閃點(°F)
30.2 °F - closed cup
閃點(°C)
-1 °C - closed cup
個人防護裝備
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
A tryptophan assay based on the glassy carbon electrode modified with a nano-sized tryptophan-imprinted polymer and multi-walled carbon nanotubes
New. J. Chem., 41(11), 4493-4502 (2017)
Catalyst-Free Suzuki-Type Coupling of Allylic Bromides with Arylboronic Acids
European Journal of Organic Chemistry, 2012(2), 264-268 (2012)
Chemical communications (Cambridge, England), (26)(26), 3943-3945 (2009-08-08)
An efficient electrosynthesis of homoallylic alcohols from allylic bromides and aldehydes in aqueous ammonia is achieved in an undivided cell fitted with a pair of zinc electrodes.
Chemical communications (Cambridge, England), 46(41), 7801-7803 (2010-09-22)
Reaction of alkynylzirconates with allyl bromides afforded β-allyl-zirconacyclopentadienes with high selectivity in unique reaction site.
The Journal of organic chemistry, 75(18), 6308-6311 (2010-08-21)
The combination of an aldehyde, an allylic bromide, and tert-butanesulfinamide in the presence of indium metal and titanium tetraethoxide allows straightforward access to homoallylamine derivatives in high yields and stereoselectivities. Moreover, the synthetic utility of the enantioenriched homoallylamine derived from
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