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Merck

337528

Sigma-Aldrich

烯丙基溴

reagent grade, 97%, contains ≤1000 ppm propylene oxide as stabilizer

别名:

3-溴-1-丙烯

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About This Item

线性分子式:
CH2=CHCH2Br
CAS号:
分子量:
120.98
Beilstein:
605308
EC號碼:
MDL號碼:
分類程式碼代碼:
12352101
PubChem物質ID:
NACRES:
NA.22

等級

reagent grade

品質等級

蒸汽密度

4.2 (vs air)

化驗

97%

形狀

liquid

自燃溫度

554 °F

包含

≤1000 ppm propylene oxide as stabilizer

expl. lim.

7.3 %

折射率

n20/D 1.469 (lit.)

bp

70-71 °C (lit.)

mp

−119 °C (lit.)

密度

1.398 g/mL at 25 °C (lit.)

官能基

alkyl halide
bromo

儲存溫度

2-8°C

SMILES 字串

BrCC=C

InChI

1S/C3H5Br/c1-2-3-4/h2H,1,3H2

InChI 密鑰

BHELZAPQIKSEDF-UHFFFAOYSA-N

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應用

使用烯丙基溴:
  • 通过Suzuki型偶联反应合成立体定向烯丙基化芳烃。
  • 应用于醛和酮的Barbier型烯丙基反应。{17]
  • 合成一个单体,1-1-(烯丙氧基)-4-硝基苯,同时合成纳米结构分子印迹聚合物,用于在生物和药物样品中选择性色氨酸的测定。

訊號詞

Danger

危險分類

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 2 - Muta. 1B - Skin Corr. 1B

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

30.2 °F - closed cup

閃點(°C)

-1 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Alizadeh T and Amjadi S
New. J. Chem., 41(11), 4493-4502 (2017)
Catalyst-Free Suzuki-Type Coupling of Allylic Bromides with Arylboronic Acids
Scrivanti A, et al.
European Journal of Organic Chemistry, 2012(2), 264-268 (2012)
Jing-Mei Huang et al.
Chemical communications (Cambridge, England), (26)(26), 3943-3945 (2009-08-08)
An efficient electrosynthesis of homoallylic alcohols from allylic bromides and aldehydes in aqueous ammonia is achieved in an undivided cell fitted with a pair of zinc electrodes.
Xiaoyu Yan et al.
Chemical communications (Cambridge, England), 46(41), 7801-7803 (2010-09-22)
Reaction of alkynylzirconates with allyl bromides afforded β-allyl-zirconacyclopentadienes with high selectivity in unique reaction site.
José C González-Gómez et al.
The Journal of organic chemistry, 75(18), 6308-6311 (2010-08-21)
The combination of an aldehyde, an allylic bromide, and tert-butanesulfinamide in the presence of indium metal and titanium tetraethoxide allows straightforward access to homoallylamine derivatives in high yields and stereoselectivities. Moreover, the synthetic utility of the enantioenriched homoallylamine derived from

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