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215074

Sigma-Aldrich

Potassium cyanate

96%

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About This Item

Linear Formula:
KOCN
CAS Number:
Molecular Weight:
81.12
Beilstein/REAXYS Number:
3594798
EC Number:
MDL number:
UNSPSC Code:
12352302
eCl@ss:
38060513
PubChem Substance ID:
NACRES:
NA.55

assay

96%

form

powder, crystals or chunks

density

2.056 g/mL at 25 °C (lit.)

SMILES string

[K+].[O-]C#N

InChI

1S/CHNO.K/c2-1-3;/h3H;/q;+1/p-1

InChI key

GKKCIDNWFBPDBW-UHFFFAOYSA-M

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General description

Potassium cyanate can be prepared by reacting urea with alkali hydroxide or carbonates at high temperatures.

Application

Potassium cyanate may be used as one of the reaction components for the synthesis of the following:
  • urea
  • hydantion
  • glycosylamine 1,2-(cyclic carbamates) {glycofurano(or pyrano)[1,2-d]oxazolidin-2-ones}
  • arylcarbamates
  • (S)-(-)-1-carbamoyl-2-methoxymethylpyrrolidine

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Irrit. 2

Storage Class

11 - Combustible Solids

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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S)-(-)-1-Amino-2-Methoxymethylpyrrolidine (SAMP) and (R)-(+)-1-Amino-2-Methoxymethylpyrrolidine (RAMP), Versatile Chiral Auxiliaries.
Enders D, et al
Organic Syntheses, 173-173 (1987)
Eagleson M.
Concise Encyclopedia Chemistry, 289-289 (1994)
Copper-Catalyzed Coupling of Arylboronic Acids with Potassium Cyanate: A New Approach to the Synthesis of Aryl Carbamates.
Kianmehr E and Baghersad MH.
Advanced Synthesis & Catalysis, 353(14-15), 2599-2603 (2011)
Jeroen N Stoop et al.
PloS one, 9(7), e102163-e102163 (2014-07-16)
The immune response to post-translationally modified antigens is a key characteristic of rheumatoid arthritis. Carbamylation is such a posttranslational modification. Recently, we demonstrated that autoantibodies recognizing carbamylated proteins are present in sera of rheumatoid arthritis. The molecular mechanisms underlying the
Eagleson M.
Concise Encyclopedia Chemistry, 503-503 (1994)

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