Skip to Content
MilliporeSigma
All Photos(1)

Documents

703206

Sigma-Aldrich

cis-Bis(isothiocyanato)bis(2,2′-bipyridyl-4,4′-dicarboxylato)ruthenium(II)

95% (NMR)

Synonym(s):

Greatcell Solar®, N-3 dye

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Empirical Formula (Hill Notation):
C26H16N6O8RuS2
CAS Number:
141460-19-7
Molecular Weight:
705.64
MDL number:
MFCD11042213
UNSPSC Code:
12352103
PubChem Substance ID:
329762438
NACRES:
NA.23

Quality Level

200

assay

95% (NMR)

form

powder

mp

>300 °C

λmax

534, 395, 312 nm (lit.)

SMILES string

S=C=N[Ru]N=C=S.OC(=O)c1ccnc(c1)-c2cc(ccn2)C(O)=O.OC(=O)c3ccnc(c3)-c4cc(ccn4)C(O)=O

InChI

1S/2C12H8N2O4.2CNS.Ru/c2*15-11(16)7-1-3-13-9(5-7)10-6-8(12(17)18)2-4-14-10;2*2-1-3;/h2*1-6H,(H,15,16)(H,17,18);;;/q;;2*-1;+2

InChI key

VMISXESAJBVFNH-UHFFFAOYSA-N

Related Categories

General description

cis-Bis(isothiocyanato)bis(2,2′-bipyridyl-4,4′-dicarboxylato)ruthenium(II) (N3 dye) is a ruthenium polypyridyl based complex that can be used as a sensitizer. It is a highly stable polymer in which the photocurrent decreases with an increase in the concentration of N3 dye.

Application

Efficent DSSCs for Direct Conversion of Sunlight to Electricity
N3 dye can be coated on electrodes for improving the sensitivity of the dye sensitized solar cells (DSSCs) which can further enhance the power conversion efficiency (PCE).

Legal Information

Product of Greatcell Solar Materials Pty Ltd.
Greatcell Solar is a registered trademark of Greatcell Solar Materials Pty Ltd.
Dyesol is a registered trademark of Greatcell Solar

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Transport-limited recombination of photocarriers in dye-sensitized nanocrystalline TiO2 solar cells
Kopidakis N, et al.
The Journal of Physical Chemistry B, 107(41), 11307-11315 (2003)
Stark effects after excited-state interfacial electron transfer at sensitized TiO2 nanocrystallites
Ardo S, et al.
Journal of the American Chemical Society, 132(19), 6696-6709 (2010)
Influence of electrolyte in transport and recombination in dye-sensitized solar cells studied by impedance spectroscopy
Fabregat-Santiago F, et al.
Solar Energy Materials and Solar Cells, 87(1-4), 117-131 (2005)
Determination of the electron lifetime in nanocrystalline dye solar cells by open-circuit voltage decay measurements
Zaban A, et al.
ChemPhysChem, 4(8), 859-864 (2003)
Ruthenium (II) Charge-Transfer Sensitizers Containing 4, 4 `-Dicarboxy-2, 2 `-bipyridine. Synthesis, Properties, and Bonding Mode of Coordinated Thio-and Selenocyanates
Kohle O, et al.
Inorganic Chemistry, 35(16), 4779-4787 (1996)
View All Related Papers

Articles

Ruthenium-Based Dyes for Dye Solar Cells

Dye solar cells (DSCs) are third generation solar cells with the promise of high efficiency combined with low production costs. While present day DSCs provide light-to-electricity conversion of up to 11%, significant further improvement is envisaged through optimized materials and novel cell and module architectures.

Efficient dye-sensitized solar cells for direct conversion of sunlight to electricity

Dye-sensitized solar cells directly convert sunlight to electricity

Organic Dyes for Efficient and Stable Dye-Sensitized Solar Cells

Over the last decade, dye-sensitized solar cells (DSSCs) have attracted much attention because these unconventional solar cells exhibit high performance and have the potential for low-cost production.

Synthesis of ZnO Aggregates and Their Application in Dye-Sensitized Solar Cells

One of the more traditional photovoltaic devices, single crystalline silicon solar cells were invented more than 50 years ago, currently make up 94% of the market. Single crystalline silicon solar cells operate on the principle of p-n junctions formed by joining p-type and n-type semiconductors.

See All

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service