431044
(Heptafluoropropyl)trimethylsilane
97%
Synonym(s):
1-(Trimethylsilyl)heptafluoropropane
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About This Item
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Quality Level
assay
97%
form
liquid
refractive index
n20/D 1.324 (lit.)
bp
88 °C (lit.)
density
1.195 g/mL at 25 °C (lit.)
functional group
fluoro
SMILES string
C[Si](C)(C)C(F)(F)C(F)(F)C(F)(F)F
InChI
1S/C6H9F7Si/c1-14(2,3)6(12,13)4(7,8)5(9,10)11/h1-3H3
InChI key
PKLASFRWKXWKII-UHFFFAOYSA-N
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Application
Reactant involved in:
- Trifluoromethylation of arenes
- Nucleophilic addition followed by intramolecular aza-Michael reactions
- Perfluoroalkylation of carbonyl compounds, aldimines and other organic substrates
Used to prepare perfluoroalkyl compounds and heptafluoro-n-propyl derivatives of phosphorus and silicon.
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The Journal of Organic Chemistry, 56, 984-984 (1991)
J. Ind. Chem. Soc., 55, 1254-1254 (1978)
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