177261

DPPF

97%

• Synonim(y): 1,1′-Ferrocenediyl-bis(diphenylphosphine), dppf
• Wzór empiryczny (zapis Hilla): C₃₄H₂₈FeP₂
• Numer CAS: 12150-46-8
• Masa cząsteczkowa: 554.38
• Numer MDL: MFCD00001422
• Kod UNSPSC: 12350000
• Identyfikator substancji w PubChem: 24850625
• NACRES: NA.22

Właściwości

• Próba: 97%
• Postać: powder
• przydatność reakcji: reaction type: Cross Couplings; reagent type: ligand; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reagent type: ligand; reaction type: Carbonylations; reagent type: ligand; reaction type: Ene Reaction; reagent type: ligand; reaction type: Heck Reaction; reagent type: ligand; reaction type: Negishi Coupling; reagent type: ligand; reaction type: Sonogashira Coupling; reagent type: ligand; reaction type: Stille Coupling; reagent type: ligand; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand; reaction type: Tsuji-Trost Reaction
• charakterystyka ekologicznej alternatywy: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 181-182 °C (dec.) (lit.)
• grupa funkcyjna: phosphine
• kategoria ekologicznej alternatywy: Aligned,
• ciąg SMILES: [Fe].[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6
• InChI: 1S/2C17H14P.Fe/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;/h2*1-14H;
• Klucz InChI: HPXNTHKXCYMIJL-UHFFFAOYSA-N

Opis

Opis ogólny

Novel functionalized furan derivatives were prepared via Pd-phosphine sequential C-C and C-O bond formation.

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Zastosowanie

Ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing.

Ruthenium-Catalyzed N-Alkylation of Amines and Sulfonamides Using Borrowing Hydrogen Methodology

Ligand used in a Pd(II)-catalyzed cross-coupling synthesis of oxazepine ring systems.

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Informacja o środkach bezpieczeństwa

• Kod klasy składowania: 11 - Combustible Solids
• Klasa zagrożenia wodnego (WGK): WGK 3
• Temperatura zapłonu (°F): Not applicable
• Temperatura zapłonu (°C): Not applicable
• Środki ochrony indywidualnej: Eyeshields, Gloves, type N95 (US)