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Merck
모든 사진(1)

문서

8.55017

Sigma-Aldrich

2-Chlorotrityl chloride resin (100-200 mesh), 1% DVB

Novabiochem®

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About This Item

UNSPSC 코드:
12352101

Quality Level

제품 라인

Novabiochem®

형태

beads

반응 적합성

reaction type: Fmoc solid-phase peptide synthesis

제조업체/상표

Novabiochem®

응용 분야

peptide synthesis

저장 온도

2-30°C

일반 설명

2-Chlorotrityl chloride resin is an extremely versatile, acid-labile resin for the solid phase immobilization of carboxylic acids [1,2,3,4,5,6, 20], alcohols [7,8,9, 20], phenols [10,11,12,13, 20] and amines [14,15,16,17,18,19,20], imidazoles [20] and hydroxylamines [21,22]. Release of these functionalities is generally achieved using 1-50% TFA in DCM containing 5% TIS, although carboxylic acids can also be cleaved from this support with AcOH/TFE/DCM [1,2,3,4,5,6],0.5% TFA in DCM, or HFIP in DCM [23].

Associated Protocols and Technical Articles
Protocols for Loading of Peptide Synthesis ResinsLiterature references

[1] K. Barlos, et al. (1989) Tetrahedron Lett., 30, 3947.
[2] K. Barlos, et al. (1989) Tetrahedron Lett., 30, 3943.
[3] K. Barlos, et al. (1991) Angew. Chem. Int. Ed. Engl., 30, 590.
[4] K. Barlos, et al. (1991) Int. J. Peptide Protein Res., 37, 513.
[5] K. Barlos, et al. (1991) Int. J. Peptide Protein Res., 38, 562.
[6] K. Barlos, et al. (1991) Int. J. Peptide Protein Res., 38, 555.
[7] H. Wenschuh, et al. in ′Peptides 1994, Proc. 23rd European Peptide Symposium′, H. Maia (Eds), ESCOM, Leiden, 1995, pp. 287.
[8] H. Wenschuh, et al. (1995) J. Org. Chem., 60, 405.
[9] B. B. Shankar, et al. (1998) Tetrahedron Lett., 39, 2447.
[10] Z. Zhu & B. Mckittrick (1998) Tetrahedron Lett., 39, 7479.
[11] U. Heinelt, et al. (2001) Bioorg. Med. Chem. Lett., 11, 227.
[12] K. J. Elgie, et al. (2000) Tetrahedron Lett., 41, 2753.
[13] S. Batra, et al. (2000) Tetrahedron Lett., 41, 5971.
[14] M. Cardno, et al. (1995) J. Chem. Soc., Chem. Commun., 2163.
[15] I. A. Nash, et al. (1996) Tetrahedron Lett., 37, 2625.
[16] W. J. Hoekstra, et al. (1997) Tetrahedron Lett., 38, 2629.
[17] J. Perumattan, et al. (1998) Mol. Div., 3, 121.
[18] J. J. McNally, et al. (1998) Tetrahedron Lett., 39,967.
[19] M. A. Youngman & S. L. Dax (1997) Tetrahedron Lett., 38, 6347.
[20] A. Bernhardt, et al. (1997) J. Peptide Res., 50, 143.
[21] S. L. Mellor, et al. (1997) Tetrahedron Lett., 38, 3311.
[22] M. M. Meloni & M. Taddei (2001) Org. Lett., 3, 337.
[23] R. Bollhagen, et al. (1994) J. Chem. Soc ., Chem. Commun., 2559.

애플리케이션

  • Efficient Synthesis of Protein Mimics by Sequential Native Chemical Ligation: This study utilized 2-Chlorotrityl chloride resin (100-200 mesh, 1% DVB) for solid-phase peptide synthesis, highlighting its effective use in complex peptide assembly processes. (Kruijtzer & Liskamp).

결합

Replaces: 01-64-0114

분석 메모

Colour (visual): white to yellow to beige
Appearance of substance (visual): beads
Loading (determined from the substitution of the Fmoc-Ala-Leu loaded resin): 1.00 - 1.80 mmol/g
Swelling Volume (in CH₂Cl₂): 2.0 - 5.0 ml/g
Total swelling volume acc. Houben Weyl (in CH2Cl2): ≥ 4.2 ml/g
The polymer matrix is copoly (styrene-1 % DVB) 100 - 200 mesh.

법적 정보

Novabiochem is a registered trademark of Merck KGaA, Darmstadt, Germany

Storage Class Code

11 - Combustible Solids

WGK

WGK 1

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable


시험 성적서(COA)

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문서

Novabiochem® has one of the most extensive ranges of linkers and derivatized resins for Fmoc solid phase peptide synthesis. These resins have varied properties with special protocols for loading and cleaving.

Novabiochem® has one of the most extensive ranges of linkers and derivatized resins for Fmoc solid phase peptide synthesis. These resins have varied properties with special protocols for loading and cleaving.

자사의 과학자팀은 생명 과학, 재료 과학, 화학 합성, 크로마토그래피, 분석 및 기타 많은 영역을 포함한 모든 과학 분야에 경험이 있습니다..

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