748854

Iodotrimethylsilane solution

1 M in dichloromethane

• 동의어(들): Iodotrimethylsilane solution, TMS iodine, TMS-I, TMSI, Trimethyliodosilane
• 실험식(Hill 표기법): C₃H₉ISi
• Molecular Weight: 200.09
• UNSPSC 코드: 12352101
• NACRES: NA.22

속성

• 형태: liquid
• 농도: 1 M in dichloromethane
• refractive index: n20/D 1.433
• density: 1.334 g/mL at 25 °C
• 저장 온도: 2-8°C

설명

일반 설명

Iodotrimethylsilane [(CH₃)₃SiI] is an important and versatile organosilicon reagent with wide applications in organic synthesis. It is used as a neutral nucleophilic reagent, trimethylsilylating agent, Lewis acid catalyst, reducing agent and dehydrating agent in many organic reactions.

애플리케이션

Iodotrimethylsilane can be used as:

• A reagent in the hydroiodation of ynamides to yield the important building blocks (E)-α-iodoenamides.
• A reagent in the synthesis of (1-iodovinyl) arenes by hydroiodation of trimethylsilyl ethynylarenes.

안전성 정보

• 픽토그램: GHS02,GHS08,GHS05,GHS07
• 신호어: Danger
• 유해 및 위험 성명서: H225,H314,H336,H351
• 예방조치 성명서: P202 - P210 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
• 표적 기관: Central nervous system
• 보충제 위험성: EUH014
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point (°F): -23.8 °F
• Flash Point (°C): -31 °C