746339

Dichlorotriphenylphosphine[bis(2-(ethylthio)ethyl)amine]ruthenium(II)

97%

• 동의어(들): Ru-SNS catalyst
• 실험식(Hill 표기법): C₂₆H₃₄Cl₂NPRuS₂
• CAS Number: 1462397-86-9
• Molecular Weight: 627.63
• MDL number: MFCD26960799
• UNSPSC 코드: 12161600
• PubChem Substance ID: 329765759
• NACRES: NA.22

속성

• 분석: 97%
• 형태: solid
• 반응 적합성: core: ruthenium; reagent type: catalyst
• 환경친화적 대안 제품 특성: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 300-310 °C
• 환경친화적 대안 카테고리: Aligned,
• SMILES string: CCSCCN([H])CCSCC.Cl[Ru]Cl.P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3
• InChI: 1S/C18H15P.C8H19NS2.2ClH.Ru/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-3-10-7-5-9-6-8-11-4-2;;;/h1-15H;9H,3-8H2,1-2H3;2*1H;/q;;;;+2/p-2
• InChI key: ZQGMNGJIEYHKBR-UHFFFAOYSA-L

설명

일반 설명

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

애플리케이션

Catalyst for hydrogenation of esters to alcohols. Greener alternative to stoichiometric hydride reagents.

Replacing Phosphorus with Sulfur for the Efficient Hydrogenation of Esters

Catalyst for the hydrogenation of esters to alcohols.

기타 정보

"The mer-SNS complexes form isomers in solution. This is due to the different arrangements of the SEt groups relative to the SNS ligand plane. Two of the isomers have eclipsed SEt groups (arranged on one side of the SNS plane), and the third isomer has staggered SEt groups (occupying the opposite sides of the SNS plane)."

법적 정보

This Product is licensed from GreenCentre Canada for non-commercial, research use only. Please contact GreenCentre Canada for information regarding commercial use of Product.

안전성 정보

• 픽토그램: GHS06
• 신호어: Danger
• 유해 및 위험 성명서: H302 + H312,H331
• 예방조치 성명서: P280 - P301 + P312 + P330 - P302 + P352 + P312 - P304 + P340 + P311
• Hazard Classifications: Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral
• Storage Class Code: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable