ALD00386

Fe(dibm)₃

• 동의어(들): Baran Olefin Cross-Coupling Catalyst, Iron tris(diisobutyrylmethane)
• 실험식(Hill 표기법): C₂₇H₄₅FeO₆
• CAS Number: 24444-72-2
• Molecular Weight: 521.49
• UNSPSC 코드: 12161600
• PubChem Substance ID: 329772664
• NACRES: NA.22

속성

• 형태: solid
• Quality Level: 100
• 반응 적합성: core: iron; reagent type: catalyst
• 환경친화적 대안 제품 특성: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 96-102 °C
• 환경친화적 대안 카테고리: Aligned,
• SMILES string: O=C([CH-]C(C(C)C)=O)C(C)C.O=C([CH-]C(C(C)C)=O)C(C)C.O=C([CH-]C(C(C)C)=O)C(C)C.[Fe+3]
• InChI: 1S/3C9H15O2.Fe/c3*1-6(2)8(10)5-9(11)7(3)4;/h3*5-7H,1-4H3;/q3*-1;+3
• InChI key: LKNJSJQVZKKQHU-UHFFFAOYSA-N

설명

일반 설명

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

애플리케이션

Iron tris(diisobutyrylmethane) was reported by Baran and coworkers to be an effective catalyst in the cross-coupling of olefins. In the presence of phenylsilane (Aldrich 335150), several highly substituted and novel functionalized C-C bonds can be formed using simple and mild reaction conditions.

기타 정보

The Baran Laboratory Blog: Functionalized Olefin Cross-Coupling

Functionalized olefin cross-coupling to construct carbon–carbon bonds

안전성 정보

• 픽토그램: GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H315,H319,H335
• 예방조치 성명서: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable