725455
Rhodium(II) triphenylacetate dimer
as complex with dichloromethane
동의어(들):
Rh2(TPA)4, Rh2(triphenylacetate)4, Rhodiumtriphenylacetate, Tetrakis(triphenylacetato)dirhodium(II)
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모든 사진(1)
About This Item
실험식(Hill 표기법):
C80H60O8Rh2 · CH2Cl2
CAS Number:
Molecular Weight:
1440.07
EC Number:
MDL number:
UNSPSC 코드:
12161600
PubChem Substance ID:
NACRES:
NA.22
추천 제품
![Bis[rhodium(α,α,α′,α′-tetramethyl-1,3-benzenedipropionic acid)] 95%](/deepweb/assets/sigmaaldrich/product/structures/102/178/d1171a49-0358-406b-8b32-04324dbf9c02/640/d1171a49-0358-406b-8b32-04324dbf9c02.png)
![[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)](/deepweb/assets/sigmaaldrich/product/structures/130/734/8846aa26-1858-458a-998d-8c306c13bf0f/640/8846aa26-1858-458a-998d-8c306c13bf0f.png)
형태
solid
반응 적합성
core: rhodium
reagent type: catalyst
reaction type: C-H Activation
mp
260-263 °C
SMILES string
ClCCl.O=C(O[Rh](OC(=O)C(c1ccccc1)(c2ccccc2)c3ccccc3)[Rh](OC(=O)C(c4ccccc4)(c5ccccc5)c6ccccc6)OC(=O)C(c7ccccc7)(c8ccccc8)c9ccccc9)C(c%10ccccc%10)(c%11ccccc%11)c%12ccccc%12
InChI
1S/4C20H16O2.CH2Cl2.2Rh/c4*21-19(22)20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18;2-1-3;;/h4*1-15H,(H,21,22);1H2;;/q;;;;;2*+2/p-4
InChI key
SRAMLXDHXNCYQM-UHFFFAOYSA-J
애플리케이션
Catalyst for:
- Amination of allene carbamates
- Allene aziridination to stereoselectively prepare cyclic cabamates
- C-H bond nitrene insertion
- Enantioselective cyclopropanation
- Preparation of cyclic oxonium ylides
신호어
Warning
유해 및 위험 성명서
Hazard Classifications
Carc. 2
Storage Class Code
11 - Combustible Solids
WGK
WGK 2
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
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