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Key Documents

536040

Sigma-Aldrich

4-4′-Dimethoxy-2-2′-bipyridine

greener alternative

97%

동의어(들):

4,4′-Dimethoxy-2,2′-bipyridyl, 4,4′-Dimethoxy-2,2′-dipyridyl

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About This Item

실험식(Hill 표기법):
C12H12N2O2
CAS Number:
Molecular Weight:
216.24
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

분석

97%

환경친화적 대안 제품 특성

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

168-171 °C (lit.)

환경친화적 대안 카테고리

SMILES string

COc1ccnc(c1)-c2cc(OC)ccn2

InChI

1S/C12H12N2O2/c1-15-9-3-5-13-11(7-9)12-8-10(16-2)4-6-14-12/h3-8H,1-2H3

InChI key

IMEVSAIFJKKDAP-UHFFFAOYSA-N

일반 설명

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalysis. Find details here.

애플리케이션

4-4′-Dimethoxy-2-2'-bipyridine may be used as a ligand in the preparation of transition metal complexes.

Ligand for greener oxidation of alcohols under aerobic conditions.

Copper(I)/ABNO-Catalyzed Aerobic Alcohol Oxidation: Alleviating Steric and Electronic Constraints of Cu/TEMPO Catalyst Systems

픽토그램

Exclamation mark

신호어

Warning

유해 및 위험 성명서

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

표적 기관

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

dust mask type N95 (US), Eyeshields, Gloves


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시험 성적서(COA)

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문서 라이브러리 방문

Julie Urgiles et al.
Dalton transactions (Cambridge, England : 2003), 46(41), 14256-14263 (2017-10-11)
Reactions of K
Photochemical isomerization of trans- to cis-[RuCl2(dppb)(4,4'-X2-2,2'-bipy)](X=-H,-NO2,-Me,-COOH,-SMe,-O=SMe,-Cl,-OMe) complexes.
Santiago MO, et al.
Polyhedron, 22(24), 3205-3211 (2003)
Synthesis and characterization of a new family of luminescent cis-(4, 4'-X2-5, 5'-Y2-2, 2'-bipyridine) 2Os (CO) Cl (PF6) complexes (X= NEt2, OMe, Me, H, Cl, Y= H; X= H, Y= Me; X= Y= Me): control of excited-state properties by bipyridyl substituents.
Della CL, et al.
Inorganic Chemistry, 29(15), 2792-2798 (1990)
Efficient osmium sensitizers containing 2,2'-bipyridine-4,4'-bisphosphonic acid ligand.
Zabri H, et al.
Journal of Photochemistry and Photobiology A: Chemistry, 166(1), 99-106 (2004)
Katia M Oliveira et al.
Journal of inorganic biochemistry, 176, 66-76 (2017-09-04)
New Ru(II) complexes with lawsone (law) characterized as trans-[Ru(law)(PPh

문서

Arylboronic acids and esters are invaluable tools for the chemical community. These powerful reagents are used for a variety of transformations, most notably the Suzuki-Miyaura cross-coupling reaction.

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