467448

Triethylsilane

97%

• 동의어(들): NSC 93579, Triethylhydrosilane, Triethylsilicon hydride
• Linear Formula: (C₂H₅)₃SiH
• CAS Number: 617-86-7
• Molecular Weight: 116.28
• Beilstein: 1098278
• EC Number: 210-535-3
• MDL number: MFCD00009018
• UNSPSC 코드: 12352103
• PubChem Substance ID: 24870410
• NACRES: NA.22

속성

• Quality Level: 200
• 분석: 97%
• 반응 적합성: reagent type: reductant
• refractive index: n20/D 1.412 (lit.)
• bp: 107-108 °C (lit.)
• density: 0.728 g/mL at 25 °C (lit.)
• SMILES string: CC[SiH](CC)CC
• InChI: 1S/C6H16Si/c1-4-7(5-2)6-3/h7H,4-6H2,1-3H3
• InChI key: AQRLNPVMDITEJU-UHFFFAOYSA-N

설명

애플리케이션

Catalyst for:

• Synthesis of a spiro-oxindole blocker of Nav1.7 for the treatment of pain
• Redox initiated cationic polymerization
• Beckmann rearrangement of cyclododecanone oxime
• Regioselective reductive coupling of enones and allenes

Catalyst reactivation after catalyst polymerization of styrene

Studies involving the prediction of organosilicon flash points

Triethylsilane can be used as:

• A reducing agent in the regioselective reductive coupling of enones and allenes.
• A reagent in the redox initiated cationic polymerization.
• A reagent in catalytic transfer hydrogenation, reduction of alkyl halides and silylation of aromatic C-H bonds, etc.
• As a reagent for the generation of indium hydride (Cl2InH) applicable as a catalyst for the intramolecular cyclization of enynes.

안전성 정보

• 픽토그램: GHS02,GHS07
• 신호어: Danger
• 유해 및 위험 성명서: H225,H315,H319,H335
• 예방조치 성명서: P210 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 2
• Flash Point (°F): 21.2 °F
• Flash Point (°C): -6 °C
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter