콘텐츠로 건너뛰기
Merck
모든 사진(1)

Key Documents

101346

Sigma-Aldrich

Dichlorophenylborane

97%

동의어(들):

NSC 93889, Phenylboron dichloride, Phenyldichloroborane

로그인조직 및 계약 가격 보기


About This Item

실험식(Hill 표기법):
C6H5BCl2
CAS Number:
Molecular Weight:
158.82
Beilstein:
2243576
MDL number:
UNSPSC 코드:
12352002
PubChem Substance ID:
NACRES:
NA.22

분석

97%

반응 적합성

reagent type: reductant

refractive index

n20/D 1.545 (lit.)

bp

66 °C/11 mmHg (lit.)

density

1.224 g/mL at 25 °C (lit.)

SMILES string

ClB(Cl)c1ccccc1

InChI

1S/C6H5BCl2/c8-7(9)6-4-2-1-3-5-6/h1-5H

InChI key

NCQDQONETMHUMY-UHFFFAOYSA-N

유사한 제품을 찾으십니까? 방문 제품 비교 안내

애플리케이션

Catalyst for:
  • Antiproliferative macrolide and cell migration inhibitor lactimidomycin
  • Enantioselective synthesis of polyketide segments using vinylogous Mukaiyama aldol reactions
  • Enantioselective Diels-Alder cycloadditions after its reaction with allo-threonine derivatives
  • Stereoselective alkylative ring opening of cyclic anhydrides
  • Cross-metathesis reaction of amino derivatives with olefins
  • Asymmetric acetate aldol reactions
  • The reaction of aryl aldehydes with styrene and (E)-β-methylstyrene
Dichlorophenylborane can be used as a catalyst for:
  • The synthesis of an antiproliferative macrolide and cell migration inhibitor lactimidomycin.
  • Enantioselective synthesis of polyketide segments using vinylogous Mukaiyama aldol reactions.
  • Enantioselective Diels-Alder cycloadditions after its reaction with allo-threonine derivatives.
  • Stereoselective alkylative ring opening of cyclic anhydrides.
  • Cross-metathesis reaction of amino derivatives with olefins.
  • Asymmetric acetate aldol reactions.

픽토그램

FlameCorrosion

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Flam. Liq. 2 - Skin Corr. 1B

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

개인 보호 장비

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


가장 최신 버전 중 하나를 선택하세요:

시험 성적서(COA)

Lot/Batch Number

적합한 버전을 찾을 수 없으신가요?

특정 버전이 필요한 경우 로트 번호나 배치 번호로 특정 인증서를 찾을 수 있습니다.

이 제품을 이미 가지고 계십니까?

문서 라이브러리에서 최근에 구매한 제품에 대한 문서를 찾아보세요.

문서 라이브러리 방문

이미 열람한 고객

Borheterocyclen, 2. Mitt.
Pailer M and Huemer H
Monatshefte fur Chemie / Chemical Monthly, 95(2), 373-378 (1964)
Total syntheses and biological reassessment of lactimidomycin, isomigrastatin and congener glutarimide antibiotics.
Micoine K, et al.
Chemistry?A European Journal , 19(23), 7370-7383 (2013)
Synthesis of a New N-Acetyl Thiazolidinethione Reagent and Its Application to a Highly Selective Asymmetric Acetate Aldol Reaction.
Zhang Y and Sammakia T
Organic Letters, 6(18), 3139-3141 (2004)
Oxazaborolidinone-Promoted Vinylogous Mukaiyama Aldol Reactions.
Simsek S, et al.
Organic Letters, 9(26), 5637-5639 (2007)
Synthesis of 1-Indanonyl Oxepanes.
Chang M Y and Lee N C
Synlett, 23(06), 867-872 (2012)

자사의 과학자팀은 생명 과학, 재료 과학, 화학 합성, 크로마토그래피, 분석 및 기타 많은 영역을 포함한 모든 과학 분야에 경험이 있습니다..

고객지원팀으로 연락바랍니다.