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Merck
모든 사진(3)

문서

417599

Sigma-Aldrich

4-Methoxyphenylboronic acid

≥95.0%

동의어(들):

(4-Methoxyphenyl)boric acid, (p-Methoxyphenyl)boronic acid, 4-Anisylboronic acid, 4-Methoxybenzeneboronic acid, p-Anisylboronic acid, p-Methoxybenzeneboronic acid

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About This Item

Linear Formula:
CH3OC6H4B(OH)2
CAS Number:
Molecular Weight:
151.96
Beilstein:
2936912
MDL number:
UNSPSC 코드:
12352103
PubChem Substance ID:
NACRES:
NA.22

분석

≥95.0%

형태

powder

mp

204-206 °C (lit.)

SMILES string

COc1ccc(cc1)B(O)O

InChI

1S/C7H9BO3/c1-11-7-4-2-6(3-5-7)8(9)10/h2-5,9-10H,1H3

InChI key

VOAAEKKFGLPLLU-UHFFFAOYSA-N

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애플리케이션

Reagent used for
  • Suzuki-Miyaura cross-coupling reactions
  • Pd-catalyzed direct arylation
  • Highly effective synthesis using palladium-catalyzed arylation Suzuki-Miyaura cross-coupling in water
  • Palladium-catalyzed stereoselective Heck-type reaction
  • Tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence
  • Copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides
  • Ruthenium catalyzed direct arylation
  • Rh-catalyzed asymmetric conjugate addition
  • Ligand-free copper-catalyzed coupling

Reagent used in Preparation of
  • Palladium(II) thiocarboxamide complexes as Suzuki coupling catalyst
  • Push-pull arylvinyldiazine chromophores with photophysical properties

기타 정보

Contains varying amounts of anhydride

픽토그램

Exclamation mark

신호어

Warning

유해 및 위험 성명서

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

표적 기관

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

dust mask type N95 (US), Eyeshields, Gloves


시험 성적서(COA)

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문서 라이브러리 방문

Maria Makrinich et al.
Solid state nuclear magnetic resonance, 84, 196-203 (2017-05-06)
The ability of various pulse types, which are commonly applied for distance measurements, to saturate or invert quadrupolar spin polarization has been compared by observing their effect on magnetization recovery curves under magic-angle spinning. A selective central transition inversion pulse
Mikhail Y Vorona et al.
Materials (Basel, Switzerland), 12(17) (2019-08-29)
Anthracene-based semiconductors are a class of molecules that have attracted interest due to their air stability, planarity, potential for strong intermolecular interactions, and favorable frontier molecular orbital energy levels. In this study seven novel 9,10-anthracene-based molecules were synthesized and their
Kosuke Ishijima et al.
Dalton transactions (Cambridge, England : 2003), 49(44), 15612-15621 (2020-09-24)
Benzo[b]arsole derivatives, being arsenic analogues of indole, were synthesized by utilizing a safely prepared arsenic precursor. The structural and photophysical properties of the obtained 2-arylbenzo[b]arsoles were experimentally and computationally studied in comparison with those of 1,2,5-triarylarsoles and 9-phenylarsafluorene. It was
M Lakshmi Kantam et al.
The Journal of organic chemistry, 71(25), 9522-9524 (2006-12-02)
N-Arylation of imidazoles and amines with arylboronic acids was accomplished with copper-exchanged fluorapatite (CuFAP) in methanol at room temperature. The products N-arylimidazoles and N-arylamines were isolated in good to excellent yields. A variety of arylboronic acids were converted to the
Elangovan Sindhuja et al.
Dalton transactions (Cambridge, England : 2003), 41(17), 5351-5361 (2012-03-09)
A simple route to synthesise palladium(II) complexes from the reaction of N-substituted pyridine-2-thiocarboxamide ligands and PdCl(2)(PPh(3))(2) has been developed. The new complexes are very soluble in common solvents and have been fully characterised (elemental analysis, FT-IR, (1)H, (31)P, (13)C-NMR), including

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