364002

(1S,2S)-(−)-1,2-Diphenylethylenediamine

97%

• 동의어(들): (1S,2S)-(−)-1,2-Diamino-1,2-diphenylethane
• Linear Formula: [C₆H₅CH(NH₂)-]₂
• CAS Number: 29841-69-8
• Molecular Weight: 212.29
• Beilstein: 3201645
• MDL number: MFCD00082751
• UNSPSC 코드: 12352116
• PubChem Substance ID: 24862409
• NACRES: NA.22

속성

• 분석: 97%
• 광학 활성: [α]20/D −102°, c = 1 in ethanol
• 광학 순도: ee: 98% (GLC)
• mp: 83-85 °C (lit.)
• 작용기: amine; phenyl
• SMILES string: N[C@H]([C@@H](N)c1ccccc1)c2ccccc2
• InChI: 1S/C14H16N2/c15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12/h1-10,13-14H,15-16H2/t13-,14-/m0/s1
• InChI key: PONXTPCRRASWKW-KBPBESRZSA-N

설명

일반 설명

1,2-Diphenylethylenediamine is a chiral molecule, generally used as a chiral resolving agent and as a precursor of the chiral auxiliary. It is also used as a chiral solvating agent in NMR study.

애플리케이션

Versatile ligand for the formation of metal complexes. Used in the synthesis of chiral tropocoronands which have potential utility in asymmetric catalysis.

포장

Bottomless glass bottle. Contents are inside inserted fused cone.

안전성 정보

• 픽토그램: GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H315,H319,H335
• 예방조치 성명서: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: dust mask type N95 (US), Eyeshields, Gloves