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Merck

CRM01342

Supelco

エトリジアゾール

certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

別名:

5-エトキシ-3-トリクロロメチル-1,2,4-チアジアゾール

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About This Item

実験式(ヒル表記法):
C5H5Cl3N2OS
CAS番号:
分子量:
247.53
MDL番号:
UNSPSCコード:
41116107
NACRES:
NA.24

グレード

certified reference material
TraceCERT®

品質水準

製品種目

TraceCERT®

シェルフライフ

limited shelf life, expiry date on the label

メーカー/製品名

Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

保管温度

2-8°C

SMILES記法

CCOc1nc(ns1)C(Cl)(Cl)Cl

InChI

1S/C5H5Cl3N2OS/c1-2-11-4-9-3(10-12-4)5(6,7)8/h2H2,1H3

InChI Key

KQTVWCSONPJJPE-UHFFFAOYSA-N

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詳細

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ. Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate. Download your certificate at: http://www.sigma-aldrich.com

Etridiazole is a fungicide primarily effective against oomycetes and widely used in controlling Pythium and Phytophthora species on agricultural and horticultural crops. Etridiazole causes the hydrolysis of cell membrane phospholipids into free fatty acids and lysophosphatides, leading to the lysis of membranes in fungi.


The drinking water standards have regulated a maximum contaminant level (MCL) for Etridiazole in treated waters. Australian drinking water guidelines set an MCL at 0.1 mg L-1. The European Union (EU) drinking water standards regulate a level for any pesticide at 0.0001 mg L-1 and the sum of all pesticides at 0.0005 mg L-1.

Etridiazole was included in Annex I to Directive 91/414/EEC on 1 June 2014 by Commission Directive 2011/29/EU and has been deemed to be approved under Regulation (EC) No 1107/2009, as per Commission Implementing Regulation (EU) No 540/2011, as amended by Commission Implementing Regulation (EU) No 541/2011. The inclusion in Annex I of Directive 91/414/EEC was restricted to uses of Etridiazole as a fungicide in non-soil bound systems in greenhouse. Maximum residue levels (MRLs) have been set according to Reg (EU) 2017/1777 for Etridiazole for various products of plant and animal origin from 0.05 to 0.4 mg/kg.

アプリケーション

The certified reference material can be used for the following:
  • To evaluate the teratogenic and developmental toxic effects of etridiazole on zebrafish embryos
  • Screening potential endophytic biofertilizers with fungicides tolerance and plant growth-promoting characteristics
  • To investigate the photodegradation of etridiazole by UV radiation at 254 nm during drinking water treatment
  • To determine the adsorption and desorption behavior of etridiazole and oxamyl on polyethylene sheets and polyvinyl chloride tubing used in horticulture
  • To develop a selective and sensitive analytical method for the determination of a carboxylic and a mercapturic acid metabolite of etridiazole in urine

おすすめ製品

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

法的情報

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

ピクトグラム

Health hazardExclamation markEnvironment

シグナルワード

Warning

危険有害性情報

危険有害性の分類

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Skin Sens. 1

保管分類コード

10 - Combustible liquids

WGK

WGK 3

引火点(°F)

310.1 °F - open cup

引火点(℃)

154.5 °C - open cup


適用法令

試験研究用途を考慮した関連法令を主に挙げております。化学物質以外については、一部の情報のみ提供しています。 製品を安全かつ合法的に使用することは、使用者の義務です。最新情報により修正される場合があります。WEBの反映には時間を要することがあるため、適宜SDSをご参照ください。

消防法

第4類:引火性液体
第三石油類
危険等級III
非水溶性液体

労働安全衛生法名称等を表示すべき危険物及び有害物

名称等を表示すべき危険物及び有害物

労働安全衛生法名称等を通知すべき危険物及び有害物

名称等を通知すべき危険物及び有害物

Jan Code

CRM01342-50MG:
CRM01342-BULK:


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試験成績書(COA)

Lot/Batch Number

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以前この製品を購入いただいたことがある場合

文書ライブラリで、最近購入した製品の文書を検索できます。

文書ライブラリにアクセスする

Adsorption experiments of etridiazole and oxamyl on polyethylene sheets and poly (vinyl chloride) tubing used in horticulture
Vuik J, et al.
Journal of Agricultural and Food Chemistry, 328-330 null
Alba Brancato et al.
EFSA journal. European Food Safety Authority, 15(3), e04736-e04736 (2017-03-09)
In accordance with Article 6 of Regulation (EC) No 396/2005, the evaluating Member State (EMS), the Netherlands, received an application from Arysta LifeScience Great Britain Limited to modify the existing maximum residue levels (MRLs) for the active substance etridiazole in various
Teratogenic and developmental toxic effects of etridiazole on zebrafish (Danio rerio) embryos
Vasamsetti BMK
Applied Biological Chemistry, 1-10 null
R T van Welie et al.
Archives of toxicology, 65(8), 625-632 (1991-01-01)
Etridiazole, 5-ethoxy-3-trichloromethyl-1,2,4-thiadiazole, was orally administered to rats and human volunteers. Two metabolites of etridiazole were synthesized: 5-ethoxy-1,2,4-thiadiazole-3-carboxylic acid (ET-CA) and N-acetyl-S-(5-ethoxy-1,2,4-thiadiazol-3-yl-methyl)-L-cysteine (ET-MA). Selective and sensitive analytical procedures to determine etridiazole, the carboxylic acid ET-CA and the mercapturic acid ET-MA in
Chao Liu et al.
Chemosphere, 76(5), 609-615 (2009-05-30)
The photodegradation of etridiazole (ETZ) in water by UV radiation at 254 nm was investigated. Results indicate that the simulated first-order rate constants decreased with the increase of initial ETZ concentration (i.e., 5, 20 and 30 microM), and did not

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