CRM44794

ホスファミドン

certified reference material, TraceCERT^®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

• 別名: 2-クロロ-N,N-ジエチル-3-(ジメチルホスホノ)クロトン酸 アミド
• 実験式（ヒル表記法）: C₁₀H₁₉ClNO₅P
• CAS番号: 13171-21-6
• 分子量: 299.69
• Beilstein: 8323501
• MDL番号: MFCD00055301
• UNSPSCコード: 41116107
• NACRES: NA.24

特性

• グレード: certified reference material; TraceCERT^®
• 品質水準: 300
• 製品種目: TraceCERT^®
• シェルフライフ: limited shelf life, expiry date on the label
• メーカー／製品名: Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
• フォーマット: neat
• 保管温度: −20°C
• SMILES記法: CCN(CC)C(=O)\C(Cl)=C(\C)OP(=O)(OC)OC
• InChI: 1S/C10H19ClNO5P/c1-6-12(7-2)10(13)9(11)8(3)17-18(14,15-4)16-5/h6-7H2,1-5H3/b9-8+
• InChI Key: RGCLLPNLLBQHPF-CMDGGOBGSA-N

詳細

詳細

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Phosphamidon is a broad-spectrum systemic organophosphorus pesticide. It is used as an insecticide against sap-feeding insects, rice-stem borers, and rice leaf beetles in crops of sugarcane, citrus fruits, commercial cotton, and nuts.
As per Regulation (EC) No. 1107/2009, repealing directive 91/414/EEC, phosphamidon is not approved for use in the European Union. But a default maximum residue limit (MRL) of 0.01 mg/kg is applicable for the presence of phosphamidon in products of plant origin, in accordance with Regulation (EC) No. 149/2008.

アプリケーション

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
The phosphamidon CRM may also find following uses:

• Determination of five organophosphorus pesticides in a medicinal herb sample using QuEChERS along with dispersive liquid-liquid microextraction (DLLME) and stacking followed by micellar electrokinetic chromatography (MEKC)
• Magnetic solid phase microextraction (MSPE) of five organophosphorus pesticides using graphene based cyanopropyltriethoxysilane as an adsorbent from cow′s milk samples and their subsequent determination by gas chromatography with micro-electron capture detector
• Investigation of residue levels of highly toxic pesticides in 6554 samples of fruits and vegetables by quadrupole time-of-flight LC/MS
• Analysis of 4 organophosphorus pesticides by gas chromatography with microelectron capture detector following their extraction using a newly synthesized magnetic hybrid material as a solid phase extraction adsorbent
• Multi-residue analysis of 44 organophosphorus pesticides by QuEChERS method combined with gas chromatography in Pogostemon cablin samples
• Detection of organophosphorus pesticides in Chinese cabbage sample by a newly designed positive photoionization-ion mobility spectrometry (PP-IMS) apparatus

法的情報

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

安全性情報

• ピクトグラム: GHS06,GHS08,GHS09
• シグナルワード: Danger
• 危険有害性情報: H300,H311,H341,H410
• 注意書き: P202 - P264 - P273 - P280 - P301 + P310 - P302 + P352 + P312
• 危険有害性の分類: Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Muta. 2
• 保管分類コード: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable