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Merck

21032

Supelco

GC 固定相

phase Carbowax 20M, bottle of 50 g

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About This Item

UNSPSCコード:
23151817

認証

meets requirements for USP G16

品質水準

形状

solid

包装

bottle of 50 g

パラメーター

60-225 °C temp. range

テクニック

gas chromatography (GC): suitable

マトリックス活性基

Carbowax 20M phase

溶解性

chloroform: soluble

McReynolds定数

17, 86, 48, 69, 56

カラムタイプ

packed GC

詳細

GC methods are divided into two classes depending on the nature of stationary phases; gas-solid chromatography (GSC) and gas-liquid chromatography (GLC). GSC has solid adsorptive material and solute particles are removed from mobile phase by electrostatic forces. GLC has a thin layer of liquid coated or bonded on the surface of an inert particle or on the walls of the column where solute particles are retained in the liquid phase based on their partition coefficients. The primary necessity of a stationary phase is to provide sample separation sustaining phase integrity over a reasonable period of time. It should be stable for the chemical and thermal changes. Selectivity, peak symmetry, analysis time, degree of separation, peak tailing are few parameters that should be considered before choosing a stationary phase. Carbowax 20M is a polar liquid phase suitable as stationary phase for gas chromatography. It consists of two units of (HC2-CH2O)600 with OH terminals connected through a hydrophobic portion. This structure of the polymer makes it suitable for being used as a solvent for polar molecules such as cyclodextrin derivatives. It exhibits good selectivity toward alcohols, diols and aromatic isomeric molecules.
GCの固定相として使用するために、純度を高く、分子量範囲を狭く、痕跡レベルの触媒や不純物を含まないように特に合成しました。

アプリケーション

Carbowax 20M may be used to test different relative amounts of crosslinking reagents by coating the inner wall of the capillary, to optimizing the capillary column performance.

保管分類コード

11 - Combustible Solids

WGK

WGK 3

引火点(°F)

Not applicable

引火点(℃)

Not applicable


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Jaiver Osorio Grisales et al.
Journal of chromatography. A, 1216(40), 6844-6851 (2009-09-01)
This paper reports the study of poly(oxyethylene) as a solvent for heptakis(2,3,6-tri-O-methyl)-beta-cyclodextrin (PM-beta-CD) and the potential of these mixtures for constructing enantioselective gas chromatography columns. Enantioseparations of volatile racemic mixtures using capillaries coated with 10-50% PM-beta-CD diluted in Carbowax 20M
George Charalambous
Chemistry of foods and beverages: Recent developments, 76-76 (1982)
Michael Gratzel
Energy Resour. Photochem. Catal. (M. Gratzel, ed.) (1983)
Nuno I P Valente et al.
Sensors (Basel, Switzerland), 18(8) (2018-07-26)
Cheese prepared from whole milk, raw and pasteurized, were analysed by an electronic nose based on piezoelectric quartz crystals and an electronic tongue based on potentiometric sensors, immediately after their preparation and along ripening (after 7 and 21 days). Whey
James P. Lodge, Jr.
Methods of Air Sampling and Analysis, 98-98 (1988)

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