B12695

ベンゾイルクロリド

ReagentPlus^®, ≥99%

• 別名: Benzoic acid chloride, alpha-chlorobenzaldehyde
• 化学式: C₆H₅COCl
• CAS番号: 98-88-4
• 分子量: 140.57
• Beilstein: 471389
• EC Number: 202-710-8
• MDL番号: MFCD00000653
• UNSPSCコード: 12352100
• PubChem Substance ID: 24891577
• NACRES: NA.21

特性

• 蒸気密度: 4.88 (vs air)
• 品質水準: 200
• 蒸気圧: 1 mmHg ( 32 °C)
• 製品種目: ReagentPlus^®
• アッセイ: ≥99%
• 形状: liquid
• 自己発火温度: 1056 °F
• expl. lim.: 4.9 %
• 屈折率: n20/D 1.553 (lit.)
• bp: 198 °C (lit.)
• mp: −1 °C (lit.)
• 密度: 1.211 g/mL at 25 °C (lit.)
• 官能基: acyl chloride; phenyl
• SMILES記法: ClC(=O)c1ccccc1
• InChI: 1S/C7H5ClO/c8-7(9)6-4-2-1-3-5-6/h1-5H
• InChI Key: PASDCCFISLVPSO-UHFFFAOYSA-N

詳細

詳細

Benzoyl chloride, an acid chloride, is a commonly used benzoylating agent. The arylation of 1,1- and 1,2-disubstituted activated alkenes using benzoyl chloride in the presence of palladium catalyst has been investigated.

アプリケーション

Benzoyl chloride may be used to synthesize:

• 4-Methoxybenzophenone via acylation of anisole in the presence of cesium-substituted dodecatungstophosphoric acid (Cs_2.5H_0.5PW₁₂O₄₀) supported on K-10 clay.
• Benzoylamino acids via acylation of amino acids in the presence of diisopropylethylamine.
• p-, o-, m-Methylbenzophenones via benzoylation of toluene in the presence of Al-promoted sulfated zirconia catalysts.

法的情報

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

安全性情報

• ピクトグラム: GHS06,GHS05
• シグナルワード: Danger
• 危険有害性情報: H302 + H312,H314,H317,H331
• 注意書き: P261 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• 危険有害性の分類: Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1
• 保管分類コード: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 1
• 引火点(°F): 161.6 °F - closed cup
• 引火点(℃): 72 °C - closed cup
• 個人用保護具 (PPE): Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter