ALD00108

3,6-Bis(methylthio)-1,2,4,5-tetrazine

≥95% (HPLC)

• 別名: 3,6-Bis(methylthio)-s-tetrazine, NSC 674352, s-Tetrazine
• 実験式（ヒル表記法）: C₄H₆N₄S₂
• CAS番号: 1672-34-0
• 分子量: 174.25
• MDL番号: MFCD02998583
• UNSPSCコード: 12352100
• PubChem Substance ID: 329772592
• NACRES: NA.22

特性

• 品質水準: 100
• アッセイ: ≥95% (HPLC)
• 形状: powder
• mp: 82-87 °C
• 保管温度: −20°C
• SMILES記法: CSC1=NN=C(SC)N=N1
• InChI: 1S/C4H6N4S2/c1-9-3-5-7-4(10-2)8-6-3/h1-2H3
• InChI Key: ROUDTSAXQIBBFZ-UHFFFAOYSA-N

詳細

アプリケーション

3,6-Bis(methylthio)-1,2,4,5-tetrazine can be used as a versatile building block in the inverse elecron demand hetero Diels-Alder reactions. The Boger Research Group has reported this powerful approach in the synthesis of alkaloids.
It can also used to synthesize:

• Substituted indoles and indolines derivatives by sequential [4+2] cycloaddition reactions.
• 3-(Methylthio)-6-(4-morpholinyl)-1,2,4,5-tetrazine by aromatic nucleophilic substitution reaction.

その他情報

Total Synthesis of Amaryllidaceae Alkaloids Utilizing Sequential Intramolecular Heterocyclic Azadiene Diels-Alder Reactions of an Unsymmetrical 1, 2, 4, 5-Tetrazin

Regioselective Inverse Electron Demand Diels-Alder Reactions of N-Acyl 6-Amino-3-(methylthio)-1, 2, 4, 5-tetrazines

安全性情報

• ピクトグラム: GHS07
• シグナルワード: Warning
• 危険有害性情報: H315,H319,H335
• 注意書き: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危険有害性の分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• ターゲットの組織: Respiratory system
• 保管分類コード: 11 - Combustible Solids
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable