931969

過塩素酸リチウム

anhydrous, ≥99.9% trace metals basis

• 別名: Perchloric acid lithium salt
• 化学式: LiClO₄
• CAS番号: 7791-03-9
• 分子量: 106.39
• MDL番号: MFCD00011079
• UNSPSCコード: 12352302
• NACRES: NA.23

特性

• グレード: anhydrous; battery grade
• 品質水準: 100
• アッセイ: ≥99.9% trace metals basis
• 形状: powder
• 環境により配慮した代替製品の特徴: Design for Energy Efficiency; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• 不純物: ≤1000 ppm (trace metals analysis)
• pH: 6.0-7.5 (25 °C, 5%, aq.sol.)
• mp: 236 °C (lit.)
• 溶解性: H₂O: 59.8 g/dL at 25 °C
• 微量陰イオン: chloride (Cl^-): ≤30 ppm; sulfate (SO₄^2-): ≤10 ppm
• 微量陽イオン: Fe: ≤5 ppm; heavy metals: ≤10 ppm
• アプリケーション: battery manufacturing
• 環境により配慮した代替製品カテゴリ: Enabling
• SMILES記法: [Li+].[O-]Cl(=O)(=O)=O
• InChI: 1S/ClHO4.Li/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1
• InChI Key: MHCFAGZWMAWTNR-UHFFFAOYSA-M

詳細

詳細

Anhydrous lithium perchlorate is a white-to-colorless crystalline salt. It is hygroscopic and deliquescent and usually stored under inert atmosphere. It is highly soluble in water and soluble in a variety of organic solvents including alcohols, acetone, acetonitrile, ethyl acetate, ethers, carbonates, and other polar organic solvents. Lithium perchlorate is a strong oxidizing agent.
Industrially, lithium perchlorate is manufactured in several ways. Most commonly, it is prepared from sodium perchlorate through a metathesis reaction with lithium chloride or lithium carbonate. Lithium perchlorate can also be prepared by direct electrochemical oxidation of lithium chloride or by reacting lithium carbonate with perchloric acid. The hydrate can be dried either by highly controlled heating or by displacing water with volatile amines, which are removed by drying under vacuum.

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アプリケーション

The primary application of lithium perchlorate is as an electrolytic salt in lithium-ion batteries. Many of the early, now-famous reports of lithium batteries used lithium perchlorate dissolved in polar organics as the electrolyte and the salt remains popular because of its high solubility, electrochemical stability, and low cost. In the search for solid electrolytes, lithium perchlorate (5-12 wt%) is often added to polyethylene oxide (PEO) and composited with ceramic nanoparticles like LLZO and LATP .
Researchers also use lithium perchlorate as an electrolytic salt in aqueous media when testing electrocatalysts. For example, recent experiments improving the electrochemical reduction of nitrogen over TiO₂ nanoparticles or gold nanoparticles use aqueous lithium perchlorate as the electrolyte.

包装

100g in poly bottle
500g in poly bottle

安全性情報

• ピクトグラム: GHS03,GHS05,GHS07
• シグナルワード: Danger
• 危険有害性情報: H272,H302,H314,H335
• 注意書き: P210 - P260 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• 危険有害性の分類: Acute Tox. 4 Oral - Eye Dam. 1 - Ox. Sol. 2 - Skin Corr. 1A - STOT SE 3
• ターゲットの組織: Respiratory system
• 保管分類コード: 5.1A - Strongly oxidizing hazardous materials
• WGK: WGK 1
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable