916803

1 M Biphenyl in THF

a precursor solution to prepare the prelithiation/presodiation reagent for disordered carbon, SiO, Sn, Sb, P, and S electrodes

• 実験式（ヒル表記法）: C₁₂H₁₀
• 分子量: 154.21
• MDL番号: MFCD00003054
• UNSPSCコード: 12352401
• NACRES: NA.23

特性

• 品質水準: 100
• 形状: liquid
• 濃度: 1 M
• 不純物: ≤1000 ppm H₂O
• アプリケーション: battery manufacturing
• 保管温度: 2-8°C

詳細

アプリケーション

This product is biphenyl (Bp) solution in anhydrous THF (1 mol/L) is a precursor reagent that could be easily handled to prepare prelithiation or presodiation reagent. By direct reaction of Li metal, it forms a strong reducing reagent of Li-Bp. The resulting Li-Bp/THF reagent has the redox potential of 0.41 V vs. Li/Li⁺, which is applicable to prelithiate most of the active materials for Li ion batteries, such as Sn, Sb, P, S, SiO and other metal oxide. On the other hand, a presodiation reagent can be prepared by reacting Bp/THF solution with Na metal. Na-Bp/THF reagent can be used to presodiate hard carbon, a promising anode material in Na ion batteries.

調製ノート

Suggested Directions for use:

• Step 1 Preparation of Prelithiation/presodiation reagent

Before use of Li metal, scrub the lithium surface to remove oxide and nitride layers.
To prepare 1 M Li-Bp/THF reagent, > 0.07 g of Li metal is added into every 10 ml of 1 M BP/THF solution
To prepare 1 M Na-Bp/THF reagent, > 0.23 g of Na metal is added into every 10 ml of 1 M BP/THF solution

• Step 2 Prelithiation/presodiation of electrodes

For a 1 cm diameter electrode with 1-3 mg acitve material per cm², soak (10-60 min, times will vary with material) the electrode in ∼0.5-1 mL of prelithiation/presodiation reagent. Discard the solution and then wash the electrode twice with THF. Longer prelithiation/presodiation time may cause electrode structure deformation, leading to a decreased discharge/charge capacity.

安全性情報

• ピクトグラム: GHS02,GHS08,GHS07,GHS09
• シグナルワード: Danger
• 危険有害性情報: H225,H302,H315,H319,H335,H336,H351,H411
• 注意書き: P210 - P273 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338 - P308 + P313
• 危険有害性の分類: Acute Tox. 4 Oral - Aquatic Chronic 2 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
• ターゲットの組織: Central nervous system, Respiratory system
• 補足的ハザード: EUH018,EUH019
• 保管分類コード: 3 - Flammable liquids
• WGK: WGK 2
• 引火点(°F): 1.4 °F
• 引火点(℃): -17 °C