903701

tBuDavePhos Pd G3

1:1 THF adduct

• 別名: t-BuDavePhos G3 Palladacycle, t-BuDavePhos Palladacycle
• 化学式: C₃₅H₄₅N₂O₃PPdS · C₄H₈O
• UNSPSCコード: 12161600
• NACRES: NA.22

特性

• 形状: powder or crystals
• 特徴: generation 3
• 反応適合性: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst; reaction type: Cross Couplings
• 官能基: phosphine
• SMILES記法: CN(C1=C(C2=C(P(C(C)(C)C)C(C)(C)C)C=CC=C2)C=CC=C1)C.NC3=C(C4=C([Pd]OS(C)(=O)=O)C=CC=C4)C=CC=C3.C5COCC5

詳細

詳細

tBuDavePhos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has a long life in solutions. tBuDavePhos Pd G3 is an excellent reagent for palladium catalyzed cross-coupling reactions. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.

アプリケーション

tBuDavePhos Pd G3 has been used as a precatalyst for the Synthesis of Aryl Sulfonamides via Palladium-Catalyzed Chlorosulfonylation of Arylboronic Acids. It may also be used for a variety of C-C and C-N cross-coupling reactions.

その他情報

Technology Spotlight: G3 and G4 Buchwald Precatalysts

Synthesis of Aryl Sulfonamides via Palladium-Catalyzed Chlorosulfonylation of Arylboronic Acids

Design and preparation of new palladium precatalysts for C-C and C-N cross-coupling reactions

安全性情報

• 保管分類コード: 11 - Combustible Solids
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable