900757

Sodium pyridine-2-sulfinate

• 別名: 2-Pyridinesulfinic acid, Sodium salt, Willis 2-pyridylsulfinates H
• 実験式（ヒル表記法）: C₅H₄NNaO₂S
• CAS番号: 24367-66-6
• 分子量: 165.15
• UNSPSCコード: 12352101
• NACRES: NA.22

特性

• 形状: powder or crystals
• 品質水準: 100
• 反応適合性: reaction type: C-C Bond Formation
• mp: 292 °C
• 官能基: sulfinic acid
• InChI: 1S/C5H5NO2S.Na/c7-9(8)5-3-1-2-4-6-5;/h1-4H,(H,7,8);/q;+1/p-1
• InChI Key: HQCGASCBCQJRDJ-UHFFFAOYSA-M

詳細

アプリケーション

This 2-pyridylsulfinate enables Suzuki-Miyaura cross coupling with aryl halides to access diverse pyridine derivatives as reported by the laboratory of Michael Willis.. No longer impeded by unstable 2-pyridyl boronates, the sulfinate alternatives provide Pd-catalyzed coupling routes to therapeutically valuable pyridine rings.

その他情報

• Technology Spotlight: Willis Pyridinates for Palladium-Catalyzed Cross-Coupling Reactions.
• Pyridine Sulfinates as General Nucleophilic Coupling Partners in Palladium-Catalyzed Cross-Coupling Reactions with Aryl Halides

安全性情報

• ピクトグラム: GHS05
• シグナルワード: Danger
• 危険有害性情報: H314
• 注意書き: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
• 危険有害性の分類: Eye Dam. 1 - Skin Corr. 1B
• 保管分類コード: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable