900756

SLAP M

≥95%

• 別名: 2-((Trimethylsilyl)methoxy)ethan-1-amine
• 実験式（ヒル表記法）: C₆H₁₇NOSi
• CAS番号: 2093935-94-3
• 分子量: 147.29
• UNSPSCコード: 12352200

特性

• アッセイ: ≥95%
• 形状: liquid
• 保管温度: 2-8°C
• SMILES記法: NCCOC[Si](C)(C)C

詳細

アプリケーション

When used with aliphatic or aromatic aldehydes, this silicon amine protocol (SLAP) reagent enables the photomediated synthesis of thiomorpholines and thiazepanes. For photocatalytic cross-coupling with this SLAP Reagent, Ir[(ppy)₂dtbbpy]PF6 (747769) is used with a recommended starting combination of Lewis acids Bi(OTf)₃ (633305) and Cu(OTf)₂ (283673) prior to subsequent substrate-specific optimization. This product was introduced in collaboration with the Bode Research Group and provides a tin-free alternative to SnAP (tin amine protocol) reagents and is well-suited for scale-up reactions.

その他情報

• Lewis Acid Induced Toggle from Ir(II) to Ir(IV) Pathways in Photocatalytic Reactions: Synthesis of Thiomorpholines and Thiazepanes from Aldehydes and SLAP Reagents
• Silicon Amine Reagents for the Photocatalytic Synthesis of Piperazines from Aldehydes and Ketones

安全性情報

• 保管分類コード: 10 - Combustible liquids
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable