900399

SLAP N-Bn Pip Reagent

95%

• 別名: N¹-Benzyl-N¹-((trimethylsilyl)methyl)ethane-1,2-diamine
• 実験式（ヒル表記法）: C₁₃H₂₄N₂Si
• CAS番号: 1908469-38-4
• 分子量: 236.43
• MDL番号: MFCD30183339
• UNSPSCコード: 12352200
• PubChem Substance ID: 329769827
• NACRES: NA.22

特性

• 品質水準: 100
• アッセイ: 95%
• フォーム: liquid (paste)
• 屈折率: n/D 1.5071
• 密度: 0.9366 g/mL
• 官能基: amine; phenyl
• 保管温度: −20°C
• SMILES記法: [Si](CN(CCN)Cc1ccccc1)(C)(C)C
• InChI: 1S/C13H24N2Si/c1-16(2,3)12-15(10-9-14)11-13-7-5-4-6-8-13/h4-8H,9-12,14H2,1-3H3
• InChI Key: OIVATBFWYNCAKW-UHFFFAOYSA-N

詳細

アプリケーション

Silicon amine protocol (SLAP) reagents, in conjunction with aldehydes and ketones, form N-unprotected piperazines via photocatalytic cross-coupling with Ir[(ppy)₂dtbbpy]PF₆ (747769). Heteroaromatic, aromatic, and aliphatic aldehydes are well tolerated, as are structurally and stereochemically complex SLAP reagents. This product was introduced in collaboration with the Bode Research Group and provides a tin-free alternative to SnAP (tin amine protocol) reagents for piperazine synthesis.

その他情報

• Technology Spotlight: SLAP Reagents for Piperazine Synthesis
• Silicon Amine Reagents for the Photocatalytic Synthesis of Piperazines from Aldehydes and Ketones
• Lewis Acid Induced Toggle from Ir(II) to Ir(IV) Pathways in Photocatalytic Reactions: Synthesis of Thiomorpholines and Thiazepanes from Aldehydes and SLAP Reagents.
• Continuous Flow Synthesis of Morpholines and Oxazepanes with Silicon Amine Protocol (SLAP) Reagents and Lewis Acid Facilitated Photoredox Catalysis

安全性情報

• ピクトグラム: GHS07
• シグナルワード: Warning
• 危険有害性情報: H315,H319,H335
• 注意書き: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危険有害性の分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• ターゲットの組織: Respiratory system
• 保管分類コード: 10 - Combustible liquids
• WGK: WGK 3
• 引火点(°F): 198.0 °F
• 引火点(℃): 92.2 °C