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Merck

792357

Sigma-Aldrich

MorDalphos Pd G3

別名:

(2-(Di-1-adamantylphosphino)morpholinobenzene)[2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate, Mesyl(2-(di-1-adamantylphosphino)morpholinobenzene)[2-(2′-amino-1,1′-biphenyl)]palladium(II),, MorDalphos-G3-palladacycle

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About This Item

実験式(ヒル表記法):
C43H55N2O4PPdS
CAS番号:
分子量:
833.37
MDL番号:
UNSPSCコード:
12161600
PubChem Substance ID:
NACRES:
NA.22

形状

solid

品質水準

特徴

generation 3

反応適合性

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings

mp

245-250 °C

官能基

phosphine

SMILES記法

NC1=C(C=CC=C1)C2=C([Pd]OS(=O)(C)=O)C=CC=C2.P([C@]34C[C@@H](C[C@@H](C4)C5)C[C@@H]5C3)([C@@]6(C[C@@H](C7)C8)C[C@H]7C[C@H]8C6)C9=CC=CC=C9N%10CCOCC%10

InChI

1S/C30H42NOP.C12H10N.CH4O3S.Pd/c1-2-4-28(27(3-1)31-5-7-32-8-6-31)33(29-15-21-9-22(16-29)11-23(10-21)17-29)30-18-24-12-25(19-30)14-26(13-24)20-30;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h1-4,21-26H,5-20H2;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1

InChI Key

XDLJAOATDSJDKP-UHFFFAOYSA-M

詳細

MorDalphos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has long life in solutions. MorDalphos Pd G3 is an excellent reagent for palladium catalyzed cross-coupling reactions. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.

保管分類コード

11 - Combustible Solids

WGK

WGK 3

引火点(°F)

Not applicable

引火点(℃)

Not applicable


試験成績書(COA)

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資料

All of the preformed catalysts used in the kit are air and moisture stable complexes in their commercially available form. Once activated by base under the reaction conditions they become sensitive to air. To best enable scale-up success, the use of standard Schlenk technique is recommended.

All of the preformed catalysts used in the kit are air and moisture stable complexes in their commercially available form. Once activated by base under the reaction conditions they become sensitive to air. To best enable scale-up success, the use of standard Schlenk technique is recommended.

All contents in the foil bag are weighed, plated, packed, and sealed in a glove box under nitrogen.

All contents in the foil bag are weighed, plated, packed, and sealed in a glove box under nitrogen.

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