735809

[2-(ジ-tert-ブチルホスフィノメチル)-6-(ジエチルアミノメチル)ピリジン]カルボニルクロロヒドリドルテニウム(II)

• 別名: Milstein触媒前駆物質, [2-(ジ-tert-ブチルホスフィノメチル)-6-(ジエチルアミノメチル)ピリジン]ルテニウム(II)クロロカルボニルヒドリド
• 実験式（ヒル表記法）: C₂₀H₃₆ClN₂OPRu
• CAS番号: 863971-62-4
• 分子量: 488.01
• MDL番号: MFCD16038117
• UNSPSCコード: 12352300
• PubChem Substance ID: 329765059
• NACRES: NA.22

特性

• 形状: powder
• 反応適合性: core: ruthenium; reagent type: catalyst
• 環境により配慮した代替製品の特徴: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• 環境により配慮した代替製品カテゴリ: Aligned,
• SMILES記法: Cl[RuH].[C-]#[O+].CCN(CC)Cc1cccc(CP(C(C)(C)C)C(C)(C)C)n1
• InChI: 1S/C19H35N2P.CO.ClH.Ru.H/c1-9-21(10-2)14-16-12-11-13-17(20-16)15-22(18(3,4)5)19(6,7)8;1-2;;;/h11-13H,9-10,14-15H2,1-8H3;;1H;;/q;;;+1;/p-1
• InChI Key: RZCAJPSOQUIHSH-UHFFFAOYSA-M

詳細

詳細

May contain up to 10% acetone and/or THF.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

アプリケーション

Precursor to active Ru catalyst for the dehydrogenative coupling of amines and alcohols to form amide bonds.

Precursor to active ruthenium catalyst for greener amide bond formation by dehydrogenative coupling of amines and alcohols.

Direct Synthesis of Amides from Alcohols and Amines with Liberation of H2

安全性情報

• ピクトグラム: GHS08,GHS07
• シグナルワード: Warning
• 危険有害性情報: H319,H351
• 注意書き: P281 - P305 + P351 + P338
• 危険有害性の分類: Carc. 2 - Eye Irrit. 2
• 補足的ハザード: EUH019
• 保管分類コード: 13 - Non Combustible Solids
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable