729353

Grubbs Catalyst^® M206

Umicore

• 別名: Grubbs Catalyst^® M2a SIPR (C933), Dichloro[1,3-bis(2,6-isopropylphenyl)-2-imidazolidinylidene](benzylidene)(tricyclohexylphosphine)ruthenium(II)
• 実験式（ヒル表記法）: C₅₂H₇₇Cl₂N₂PRu
• CAS番号: 373640-75-6
• 分子量: 933.13
• UNSPSCコード: 12161600
• PubChem Substance ID: 329764471
• NACRES: NA.22

特性

• 形状: solid
• mp: 176-181 °C
• 保管温度: 2-8°C
• SMILES記法: C1CCC(CC1)P(C2CCCCC2)C3CCCCC3.CC(C)c4cccc(C(C)C)c4N5CCN(C5[Ru](Cl)(Cl)=Cc6ccccc6)c7c(cccc7C(C)C)C(C)C
• InChI: 1S/C27H39N2.C18H33P.C7H6.2ClH.Ru/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;;;/h9-14,17-21H,15-16H2,1-8H3;16-18H,1-15H2;1-6H;2*1H;/q;;;;;+2/p-2
• InChI Key: VWYWCKUDPDENIJ-UHFFFAOYSA-L

詳細

アプリケーション

• Bulky NHC ligand results in faster initiation than the Grubbs 2^nd Generation Catalyst.
• Has enabled lower catalyst loadings in some applications.

Grubbs Catalyst^® M2a SIPr is a second generation Grubb′s catalyst used to catalyze olefin metathesis which low catalyst loading. This is also used in synthesizing variety of highly active second generation fast-initiation Hoveyda type ruthenium catalysts.

その他情報

Ruthenium-based catalysts for olefin metathesis

Grubbs Catalyst^® Technology for Olefin Metathesis by Sigma-Aldrich

法的情報

Product of Umicore

Product License
This product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through Sigma-Aldrich, its affiliates or their authorized distributors conveys to the buyer a limited, one-time, non-exclusive, non-transferable, non-assignable license. Buyer′s use of this product may infringe patents owned or controlled by third parties. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the patent rights of third parties or exceed the scope of the license granted herein.

For any further information on product please refer to your local Umicore PMC contact at http://www.pmc.umicore.com

Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG

安全性情報

• ピクトグラム: GHS02
• シグナルワード: Warning
• 危険有害性情報: H228
• 注意書き: P210
• 危険有害性の分類: Flam. Sol. 2
• 保管分類コード: 4.1B - Flammable solid hazardous materials
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable