649066

Chlorodicyclopentylphosphine

97%

• 別名: ジシクロペンチルクロロホスフィン, ジシクロペンチルホスフィンクロリド
• 実験式（ヒル表記法）: C₁₀H₁₈ClP
• CAS番号: 130914-24-8
• 分子量: 204.68
• MDL番号: MFCD06798131
• UNSPSCコード: 12352101
• PubChem Substance ID: 24883629
• NACRES: NA.22

特性

• アッセイ: 97%
• 反応適合性: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling
• 密度: 1.069 g/mL at 25 °C (lit.)
• 官能基: phosphine
• SMILES記法: ClP(C1CCCC1)C2CCCC2
• InChI: 1S/C10H18ClP/c11-12(9-5-1-2-6-9)10-7-3-4-8-10/h9-10H,1-8H2
• InChI Key: QTYRJBRBODDGCQ-UHFFFAOYSA-N

詳細

詳細

Chlorodicyclopentylphosphine is a phosphine precursor for ligand preparation in Negishi and Suzuki coupling reactions.

http://citeseerx.ist.psu.edu/viewdoc/download?doi=10.1.1.259.5096&rep=rep1&type=pdf

アプリケーション

Chlorodicyclopentylphosphine may be used to prepare:

• Cp,Cp-MannOP, a chiral diphosphinite ligand by reacting with mannitol.[Cp=cyclopentyl; Mann=mannitol]
• (S)-Cp,Cp-oxoProNOP, a bis(dicycloalkylphosphino) amidophosphine-phosphinite ligand by reacting with (S)-5-(hydroxymethyl)-2-pyrrolidinone
• L^cPeNiCl, a precursor for preparing L^cPeNiH, which is an efficient catalyst for the reduction of CO₂[cPe=cyclopentyl]

安全性情報

• ピクトグラム: GHS05
• シグナルワード: Danger
• 危険有害性情報: H314
• 注意書き: P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363 - P405
• 危険有害性の分類: Skin Corr. 1B
• 補足的ハザード: EUH014
• 保管分類コード: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3
• 引火点(°F): >230.0 °F - closed cup
• 引火点(℃): > 110 °C - closed cup
• 個人用保護具 (PPE): Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter