498041

シクロペンチル亜鉛ブロミド 溶液

0.5 M in THF

• 別名: Bromo(cyclopentyl)zinc, Bromocyclopentylzinc
• 化学式: C₅H₉ZnBr
• CAS番号: 171860-68-7
• 分子量: 214.42
• MDL番号: MFCD00671991
• UNSPSCコード: 12352103
• PubChem Substance ID: 24873166
• NACRES: NA.22

特性

• 濃度: 0.5 M in THF
• 密度: 0.955 g/mL at 25 °C
• 保管温度: 2-8°C
• SMILES記法: Br[Zn]C1CCCC1
• InChI: 1S/C5H9.BrH.Zn/c1-2-4-5-3-1;;/h1H,2-5H2;1H;/q;;+1/p-1
• InChI Key: GOPYCBPMCCJYSN-UHFFFAOYSA-M

詳細

アプリケーション

Cyclopentylzinc bromide is an organozinc reagent that can be used in:

• The synthesis of polyfunctional indoles by reacting with various aryldiazonium salts via Fischer indole synthesis.
• Negishi cross-coupling reactions with various haloarenes in presence of Pd-complex catalyst.
• The preparation of aryl alkyl ketones by alkylation of aryl N-methyl-N-tosyl or N-benzyl-N-(tert-butoxycarbonyl) amide derivatives in the presence of Ni catalyst and imidazolidinylidene ligand.

法的情報

Rieke^® Metals, Inc.の製品です。

安全性情報

• ピクトグラム: GHS02,GHS08,GHS07
• シグナルワード: Danger
• 危険有害性情報: H225,H261,H302,H315,H319,H335,H351
• 注意書き: P210 - P231 + P232 - P280 - P370 + P378 - P402 + P404 - P403 + P235
• 危険有害性の分類: Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3 - Water-react 2
• ターゲットの組織: Respiratory system
• 補足的ハザード: EUH019
• 保管分類コード: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• 引火点(°F): 1.4 °F - closed cup
• 引火点(℃): -17 °C - closed cup