439061

(−)-イソプレゴール

99%

• 別名: (1R,2S,5R)-2-イソプロペニル-5-メチルシクロヘキサノール, (1R,3R,4S)-p-メンタ-8-エン-3-オール
• 実験式（ヒル表記法）: C₁₀H₁₈O
• CAS番号: 89-79-2
• 分子量: 154.25
• Beilstein: 1906573
• EC Number: 201-940-6
• MDL番号: MFCD00134655
• UNSPSCコード: 12352205
• PubChem Substance ID: 24867323
• NACRES: NA.22

特性

• 品質水準: 100
• アッセイ: 99%
• フォーム: liquid
• 光学活性: [α]20/D −22°, neat
• 屈折率: n20/D 1.471 (lit.)
• bp: 212 °C (lit.)
• 密度: 0.912 g/mL at 25 °C (lit.)
• 官能基: hydroxyl
• SMILES記法: C[C@@H]1CC[C@H]([C@H](O)C1)C(C)=C
• InChI: 1S/C10H18O/c1-7(2)9-5-4-8(3)6-10(9)11/h8-11H,1,4-6H2,2-3H3/t8-,9+,10-/m1/s1
• InChI Key: ZYTMANIQRDEHIO-KXUCPTDWSA-N

詳細

詳細

Isopulegol is monoterpene alcohol, a useful ingredient for the production of fragrances in perfume industries. It is also used as a starting material in the manufacture of menthol by the hydrogenation process. Menthol is an important component in cosmetics, pharmaceuticals, and toothpaste.

アプリケーション

(−)-Isopulegol can be used as a starting material for the enantioselective preparation of:      

• 8-arylmenthols by Smiles-Truce rearrangement of aryl sulfonates.,·        
• Stereoisomers of 5,9-dimethylpentadecane.
• Octahydro-2H-chromen-4-ol by Prins cyclization with vanillin in the presence of montmorillonite clay as the catalyst.     
• p-menthane-3,8,9-triol by catalytic Sharpless dihydroxylation.

安全性情報

• ピクトグラム: GHS07
• シグナルワード: Warning
• 危険有害性情報: H302,H315,H319,H335
• 注意書き: P261 - P264 - P270 - P301 + P312 - P302 + P352 - P305 + P351 + P338
• 危険有害性の分類: Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• ターゲットの組織: Respiratory system
• 保管分類コード: 10 - Combustible liquids
• WGK: WGK 1
• 引火点(°F): 172.4 °F - closed cup
• 引火点(℃): 78 °C - closed cup
• 個人用保護具 (PPE): Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter