423602

Ethyl cis-3-iodoacrylate

98%

• 化学式: ICH=CHCO₂C₂H₅
• CAS番号: 31930-36-6
• 分子量: 226.01
• MDL番号: MFCD00209584
• UNSPSCコード: 12352100
• PubChem Substance ID: 24866512
• NACRES: NA.22

特性

• 品質水準: 200
• アッセイ: 98%
• フォーム: liquid
• 屈折率: n20/D 1.533 (lit.)
• bp: 85 °C/20 mmHg (lit.)
• 密度: 1.765 g/mL at 25 °C (lit.)
• 官能基: ester; iodo
• 保管温度: 2-8°C
• SMILES記法: [H]\C(I)=C(/[H])C(=O)OCC
• InChI: 1S/C5H7IO2/c1-2-8-5(7)3-4-6/h3-4H,2H2,1H3/b4-3-
• InChI Key: AELYFQSZXFFNGP-ARJAWSKDSA-N

詳細

詳細

Ethyl cis-3-iodoacrylate (cis-ethyl-β-iodoacrylate, ethyl (Z)-β-iodoacrylate) is Z-vinyl iodide derivative. It is reported to be prepared from ethyl propiolate by treating with sodium iodide. Its Suzuki coupling reaction with cyclic vinyl boronic acids has been studied.

アプリケーション

Ethyl cis-3-iodoacrylate may be used in the synthesis of the following:

• vinyl sulfides
• (Z)-1-iodohept-1-en-3-ol
• (E)-1-iodohept-1-en-3-ol
• (Z)-β-iodoacrolein
• 6-oxo-M₁Guo

安全性情報

• ピクトグラム: GHS07
• シグナルワード: Warning
• 危険有害性情報: H315,H319,H335
• 注意書き: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危険有害性の分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• ターゲットの組織: Respiratory system
• 保管分類コード: 10 - Combustible liquids
• WGK: WGK 3
• 引火点(°F): 210.2 °F - closed cup
• 引火点(℃): 99 °C - closed cup
• 個人用保護具 (PPE): Eyeshields, Gloves, type ABEK (EN14387) respirator filter