376159

(Trimethylsilyl)methyl isocyanide

97%

• 別名: (Isocyanomethyl)trimethylsilane
• 化学式: (CH₃)₃SiCH₂NC
• CAS番号: 30718-17-3
• 分子量: 113.23
• Beilstein: 3930556
• MDL番号: MFCD00043056
• UNSPSCコード: 12352100
• PubChem Substance ID: 24863423
• NACRES: NA.22

特性

• 品質水準: 200
• アッセイ: 97%
• 形状: liquid
• 屈折率: n20/D 1.416 (lit.)
• bp: 52-53 °C/35 mmHg (lit.)
• 密度: 0.803 g/mL at 25 °C (lit.)
• 官能基: amine; isonitrile
• 保管温度: −20°C
• SMILES記法: C[Si](C)(C)C[N+]#[C-]
• InChI: 1S/C5H11NSi/c1-6-5-7(2,3)4/h5H2,2-4H3
• InChI Key: OLSTVZKPVGMQKB-UHFFFAOYSA-N

詳細

詳細

Synthesis of (trimethylsilyl)methyl isocyanide and its reaction with protic nucleophiles has been reported. An improved preparation of (trimethylsilyl)methyl isocyanide is reported. Reaction of (trimethylsilyl)methyl isocyanide with (η²-formaldehyde)zirconocene complex is reported to yield insertion products.

アプリケーション

(Trimethylsilyl)methyl isocyanide may be used in the preparation of isocyanomethylenetriphenylphosphorane.

包装

底の開いたガラス瓶内容物は内部に挿入され接着された円錐部に入っています。

安全性情報

• ピクトグラム: GHS02,GHS06
• シグナルワード: Danger
• 危険有害性情報: H225,H301 + H311 + H331
• 注意書き: P210 - P233 - P280 - P301 + P310 - P303 + P361 + P353 - P304 + P340 + P311
• 危険有害性の分類: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2
• 保管分類コード: 3 - Flammable liquids
• WGK: WGK 3
• 引火点(°F): <59.0 °F - closed cup
• 引火点(℃): < 15 °C - closed cup
• 個人用保護具 (PPE): Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter