349925

(+)-Chloromethyl menthyl ether

97%

• 実験式（ヒル表記法）: C₁₁H₂₁ClO
• CAS番号: 103128-76-3
• 分子量: 204.74
• MDL番号: MFCD09039273
• UNSPSCコード: 12352101
• PubChem Substance ID: 24861717
• NACRES: NA.22

特性

• アッセイ: 97%
• フォーム: liquid
• 光学活性: [α]24/D +181.0°, c = 2 in methylene chloride
• 光学純度: ee: 98% (GLC)
• 屈折率: n20/D 1.467 (lit.)
• bp: 72 °C/0.4 mmHg (lit.)
• 密度: 0.994 g/mL at 25 °C (lit.)
• 官能基: chloro; ether
• 保管温度: −20°C
• SMILES記法: CC(C)[C@H]1CC[C@H](C)C[C@@H]1OCCl
• InChI: 1S/C11H21ClO/c1-8(2)10-5-4-9(3)6-11(10)13-7-12/h8-11H,4-7H2,1-3H3/t9-,10+,11-/m0/s1
• InChI Key: XOPLTFUYFXWFGB-AXFHLTTASA-N

詳細

アプリケーション

(+)-Chloromethyl menthyl ether can be used:

• As a starting material for the synthesis of 1-methyl-3-(+)-methylmenthoxide imidazolium chloride, a key intermediate for the preparation of Ag(I) N-heterocyclic carbene, applicable as a catalyst in the diboration of alkenes.
• As a substrate in the synthesis of commercially important O-substituted α-methoxymethylketones.
• To determine enantiomeric excess (ee) of an iron chiral auxiliary named [Fe(CO)(η;⁵- C₂H₅)(PPh₃)COCH₃].

安全性情報

• ピクトグラム: GHS07
• シグナルワード: Warning
• 危険有害性情報: H315,H319,H335
• 注意書き: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危険有害性の分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• ターゲットの組織: Respiratory system
• 保管分類コード: 10 - Combustible liquids
• WGK: WGK 3
• 引火点(°F): 224.6 °F - closed cup
• 引火点(℃): 107 °C - closed cup
• 個人用保護具 (PPE): Eyeshields, Gloves, type ABEK (EN14387) respirator filter