237051
Aluminum chloride
ReagentPlus®, 99%
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About This Item
Formula condensata:
AlCl3
Numero CAS:
Peso molecolare:
133.34
Numero CE:
Numero MDL:
Codice UNSPSC:
12352302
eCl@ss:
38120507
ID PubChem:
NACRES:
NA.21
Prodotti consigliati
Tensione di vapore
1 mmHg ( 100 °C)
Nome Commerciale
ReagentPlus®
Saggio
99%
Forma fisica
powder
Impiego in reazioni chimiche
reagent type: catalyst
core: aluminum
pH
2.4 (20 °C, 100 g/L)
Punto di fusione
190 °C (lit.)
Stringa SMILE
Cl[Al](Cl)Cl
InChI
1S/Al.3ClH/h;3*1H/q+3;;;/p-3
VSCWAEJMTAWNJL-UHFFFAOYSA-K
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Categorie correlate
Descrizione generale
Aluminum chloride is an alcohol-soluble lewis acid.† Aluminum chloride mixed with sodium borohydride, in diglyme in a molar ratio affords a mixture having strong reducing properties.† It was reported to promote the Friedel-Crafts acylation reaction between 4-tert-butylbenzoyl chloride and mesitylene.†
Applicazioni
Aluminum chloride was used for the following studies:
- Polymerization of benzene to afford p-polyphenyl.
- As a catalyst for the Friedel-Crafts acylation of buckymetallocenes with the acid chlorides.
- As a catalyst for the colorimetric microassay for the determination of lipid hydroperoxides.
Caratteristiche e vantaggi
The vapor-phase co-reductions with other metal halides by hydrogen results in finely divided intermetallics with applications as structural materials or compounds with useful thermoelectric, magnetic, and oxidation-resistance properties. Aluminum nitride can be synthesized from the elemnts with AlCl3 added to help facilitate crystallization.
Note legali
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
Avvertenze
Danger
Indicazioni di pericolo
Classi di pericolo
Eye Dam. 1 - Skin Corr. 1B
Rischi supp
Codice della classe di stoccaggio
8B - Non-combustible corrosive hazardous materials
Classe di pericolosità dell'acqua (WGK)
WGK 1
Punto d’infiammabilità (°F)
Not applicable
Punto d’infiammabilità (°C)
Not applicable
Certificati d'analisi (COA)
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I clienti hanno visto anche
Detection of Alternative Oxidase Expression in Arabidopsis thaliana Protoplasts Treated with Aluminium.
Liu J, et al.
Bio-protocol, 5(13) (2015)
p-Polyphenyl from Benzene-Lewis Acid Catalyst-Oxidant. Reaction Scope and Investigation of the Benzene-Aluminum Chloride-Cupric Chloride System1.
Kovacic P and Oziomek J.
The Journal of Organic Chemistry, 29(1), 100-104 (1964)
Shutao Wang et al.
Advanced science (Weinheim, Baden-Wurttemberg, Germany), 5(4), 1700712-1700712 (2018-05-04)
In the search for low-cost and large-scale stationary storage of electricity, nonaqueous aluminum chloride-graphite batteries (AlCl3-GBs) have received much attention due to the high natural abundances of their primary constituents, facile manufacturing, and high energy densities. Much research has focused
Yutaka Matsuo et al.
Dalton transactions (Cambridge, England : 2003), 43(20), 7407-7412 (2013-10-26)
Acylated buckyferrocene and ruthenocene, Fe(η(5)-C60Me5)(η(5)-C5H4COR) (R = Me, Ph, and CH[double bond, length as m-dash]CHPh) and Ru(η(5)-C60Me5)(η(5)-C5H4COR) (R = Me and Ph), were obtained by Friedel-Crafts acylation of the parent buckymetallocenes with the corresponding acid chlorides and aluminum chloride in
Rajkumar Kore et al.
Dalton transactions (Cambridge, England : 2003), 47(23), 7795-7803 (2018-06-01)
Two solids of differing Lewis acidities, triethylammonium tetrachlorozincate ([HN222]2[ZnCl4]) and AlCl3, have been combined across 0.1 to 0.9 mole fractions (with respect to [HN222]2[ZnCl4]), and homogeneous solid double salts or mixed metal [HN222]2x[(1 - x)AlCl3 + xZnCl4] double salt ionic
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