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Key Documents

M1875

Sigma-Aldrich

Sodium malonate dibasic monohydrate

≥98% (non-aqueous titration)

Sinonimo/i:

Malonic acid disodium salt monohydrate, Propanedioic acid disodium salt monohydrate

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About This Item

Formula condensata:
CH2(CO2Na)2 · H2O
Numero CAS:
Peso molecolare:
166.04
Beilstein:
3772420
Numero CE:
Numero MDL:
Codice UNSPSC:
12352100
ID PubChem:
NACRES:
NA.22

Saggio

≥98% (non-aqueous titration)

Stringa SMILE

O.[Na].OC(=O)CC(O)=O

InChI

1S/C3H4O4.2Na/c4-2(5)1-3(6)7;;/h1H2,(H,4,5)(H,6,7);;/q;2*+1/p-2
PRWXGRGLHYDWPS-UHFFFAOYSA-L

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Applicazioni

Sodium malonate dibasic monohydrate can be used as a ligand to synthesize:
  • Bis(cyclopentadienyl)molybdenum malonate using molybdenocene dichloride in the presence of water.
  • Malonato complexes of manganese using manganese dichloride and 1,10-phenanthroline in the presence of methanol.
  • Metal-organic based polymeric complex using transition metal compound and urotropine.

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

Eyeshields, Gloves, type N95 (US)


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Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry, 14(7), 1109-1117 (2009-06-19)
Two water-soluble molybdenocene complexes containing oxygen chelating ligands, maltolato and malonate, have been synthesized to elucidate the role of the ancillary ligands in the molybdenocene cytotoxic activity. The structural characterizations of these species by 1H NMR and IR spectroscopies suggest
Sanjit Konar et al.
Inorganic chemistry, 42(8), 2545-2552 (2003-04-15)
Two new metal-organic based polymeric complexes, [Cu(4)(O(2)CCH(2)CO(2))(4)(L)].7H(2)O (1) and [Co(2)(O(2)CCH(2)CO(2))(2)(L)].2H(2)O (2) [L = hexamethylenetetramine (urotropine)], have been synthesized and characterized by X-ray crystal structure determination and magnetic studies. Complex 1 is a 1D coordination polymer comprising a carboxylato bridged Cu(4)
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A detailed inhibition study of five carbonic anhydrase (CA, EC 4.2.1.1) isozymes with carboxylates including aliphatic (formate, acetate), dicarboxylic (oxalate, malonate), hydroxy/keto acids (l-lactate, l-malate, pyruvate), tricarboxylic (citrate), or aromatic (benzoate, tetrafluorobenzoate) representatives, some of which are important intermediates in

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