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Merck
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61405

Sigma-Aldrich

Methyl levulinate

greener alternative

≥98.0%

Sinonimo/i:

4-Oxopentanoic acid methyl ester, 4-Oxovaleric acid methyl ester, Methyl β-acetylpropionate, Methyl 4-oxopentanoate, Methyl 4-oxovalerate, Methyl levulate

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About This Item

Formula condensata:
CH3COCH2CH2COOCH3
Numero CAS:
Peso molecolare:
130.14
Beilstein:
1754008
Numero CE:
Numero MDL:
Codice UNSPSC:
12352100
ID PubChem:
NACRES:
NA.22

Livello qualitativo

Saggio

≥98.0%

Caratteristiche più verdi

Safer Solvents and Auxiliaries
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

Indice di rifrazione

n20/D 1.422

P. ebollizione

193-195 °C (lit.)

Densità

1.051 g/mL at 20 °C (lit.)

Gruppo funzionale

ester
ketone

Categoria alternativa più verde

Stringa SMILE

COC(=O)CCC(C)=O

InChI

1S/C6H10O3/c1-5(7)3-4-6(8)9-2/h3-4H2,1-2H3
UAGJVSRUFNSIHR-UHFFFAOYSA-N

Descrizione generale

Methyl levulinate can be synthesized from glucose in the presence of a few drops of dilute sulfuric acid in methanol.
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Applicazioni

Methyl levulinate can undergo Meerwein–Ponndorf–Verley (MPV) reduction in the presence of lewis acid zeolite like Hf-beta to give 4-hydroxypentanoates.

Codice della classe di stoccaggio

10 - Combustible liquids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

161.6 °F - closed cup

Punto d’infiammabilità (°C)

72 °C - closed cup

Dispositivi di protezione individuale

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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I clienti hanno visto anche

Wan-Chu Yun et al.
Journal of colloid and interface science, 543, 52-63 (2019-02-20)
While zirconium (Zr)-based metal organic frameworks (MOFs) are promising for conversion of levulinic acid (LA) to γ-valerolactone (GVL) through catalytic transform hydrogenation (CTH), these reported Zr MOFs for LA conversion must be synthesized in toxic dimethylformamide (DMF). From the viewpoint
"Extremely low sulfuric acid catalyst system for synthesis of methyl levulinate from glucose"
<BIG>Peng L, et al.</BIG>
Industrial Crops and Products, 40, 136-144 (2012)
Xiaoyu Wu et al.
Carbohydrate research, 358, 37-39 (2012-07-31)
One-pot preparation of methyl levulinate (MLA) from cellulose in near-critical methanol was studied. Acids containing SO(3)H group were proven to be effective catalysts for the production of MLA from cellulose's catalytic alcoholysis. The effects of different reaction conditions, such as
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"Investigation of the reaction kinetics of isolated Lewis acid sites in beta zeolites for the Meerwein?Ponndorf?Verley reduction of methyl levulinate to ?-valerolactone"
<BIG>Luo.YH, et al.</BIG>
J. Catal., 320, 198-207 (2014)

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