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H40807

Sigma-Aldrich

5-idrossimetil-2-furaldeide

99%

Sinonimo/i:

5-(idrossimetil)furfurale, 5-idrossimetil-2-furancarbossaldeide, HMF

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About This Item

Formula empirica (notazione di Hill):
C6H6O3
Numero CAS:
67-47-0
Peso molecolare:
126.11
Beilstein:
110889
Numero CE:
200-654-9
Numero MDL:
MFCD00003234
Codice UNSPSC:
12352100
ID PubChem:
24895618
NACRES:
NA.22

Livello qualitativo

200

Saggio

99%

Indice di rifrazione

n20/D 1.562 (lit.)

P. ebollizione

114-116 °C/1 mmHg (lit.)

Punto di fusione

28-34 °C (lit.)

Densità

1.243 g/mL at 25 °C (lit.)

Temperatura di conservazione

2-8°C

Stringa SMILE

[H]C(=O)c1ccc(CO)o1

InChI

1S/C6H6O3/c7-3-5-1-2-6(4-8)9-5/h1-3,8H,4H2
NOEGNKMFWQHSLB-UHFFFAOYSA-N

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Categorie correlate

Applicazioni

5-Hydroxymethyl-2-furaldehyde (HMF) can be used in the synthesis of:
  • Furan-2,5-dicarboxaldehyde (FDA) using a vanadyl phosphate-based catalyst via selective oxidation.
  • Prepolymer and antiviral precursor, 5,5′-oxy(bismethylene)-2-furaldehyde (OBMF) using solid acid catalysts via etherification reaction.
  • Diformylfurane (DFF) by aerobic oxidation using pyridine-vanadyl complexes.

Pittogrammi

Exclamation mark
GHS07

Avvertenze

Warning

Indicazioni di pericolo

H315,H319

Classi di pericolo

Eye Irrit. 2 - Skin Irrit. 2

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 2

Punto d’infiammabilità (°F)

174.2 °F - closed cup

Punto d’infiammabilità (°C)

79 °C - closed cup

Dispositivi di protezione individuale

dust mask type N95 (US), Eyeshields, Gloves

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Certificati d'analisi (COA)

Lot/Batch Number
WXBD5409V
WXBD4506V
WXBD2079V
WXBD1198V
WXBC9665V

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Sigma-Aldrich

E32754

4,6-O-Ethylidene-α-D-glucose

Furfural analytical standard

Supelco

04623

Furfural

5-Hydroxymethyl-2-furancarboxylic acid ≥95%

Sigma-Aldrich

902845

5-Hydroxymethyl-2-furancarboxylic acid

Furfuryl alcohol 98%

Sigma-Aldrich

185930

Furfuryl alcohol

5-Acetoxymethyl-2-furaldehyde 99%

Sigma-Aldrich

145424

5-Acetoxymethyl-2-furaldehyde

Chemicals from biomass: Aerobic oxidation of 5-hydroxymethyl-2-furaldehyde into diformylfurane catalyzed by immobilized vanadyl-pyridine complexes on polymeric and organofunctionalized mesoporous supports.
Navarro OC, et al.
Topics in Catalysis, 52(3), 304-314 (2009)
Chemicals from biomass: Etherification of 5-hydroxymethyl-2-furfural (HMF) into 5, 5?(oxy-bis (methylene)) bis-2-furfural (OBMF) with solid catalysts.
Casanova O, et al.
J. Catal., 275(2), 236-242 (2010)
Selective oxidation of 5-hydroxymethyl-2-furaldehyde to furan-2, 5-dicarboxaldehyde by catalytic systems based on vanadyl phosphate.
Carlini C, et al.
Applied Catalysis A: General, 289(2), 197-204 (2005)
Yin-Ying Lee et al.
Physical chemistry chemical physics : PCCP, 14(40), 13914-13917 (2012-09-20)
Mesoporous silica nanoparticles functionalized with both sulfonic acid (HSO(3)) and ionic liquid (ILs) were synthesized and applied as effective and recyclable catalysts for generating 5-hydroxymethylfurfural (HMF) from fructose. For the first time a high HMF yield of 72.5% was achieved
Lilong Zhou et al.
Bioresource technology, 129, 450-455 (2012-12-26)
A new kind of bifunctional ionic liquid catalysts was synthesized to degrade microcrystalline cellulose in [BMIM]Cl at atmospheric pressure. The effects of reaction temperature, amount of catalysts, reaction time, ionic liquid purity and cellulose concentration on conversion were investigated. At
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Protocolli

HPLC Analysis of Furans on Ascentis® Express Phenyl-Hexyl as listed in ASTM method D5837-99

Separation of 5-Hydroxymethyl-2-furaldehyde; Furfuryl alcohol; Furfural; 2-Furyl methyl ketone; 5-Methyl-2-furaldehyde

HPLC Analysis of Furans on Ascentis® Express C18

HPLC Analysis of Furans on Ascentis® Express C18

Global Trade Item Number

SKUGTIN
H40807-1G4061835557134
H40807-5G4061835512621
H40807-100G
H40807-250MG4061835557141

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