393193

Hydrocinnamaldehyde

technical grade, 90%

• Sinonimo/i: 3-Phenylpropionaldehyde
• Formula condensata: C₆H₅CH₂CH₂CHO
• Numero CAS: 104-53-0
• Peso molecolare: 134.18
• Beilstein: 1071910
• Numero CE: 203-211-8
• Numero MDL: MFCD00007021
• Codice UNSPSC: 12352100
• ID PubChem: 24864504
• NACRES: NA.22

Proprietà

• Grado: technical grade
• Livello qualitativo: 100
• Saggio: 90%
• Stato: liquid
• Impurezze: <5% 3-phenyl-1-propanol
• Indice di rifrazione: n20/D 1.523 (lit.)
• P. ebollizione: 97-98 °C/12 mmHg (lit.)
• Densità: 1.019 g/mL at 25 °C (lit.)
• Gruppo funzionale: aldehyde; phenyl
• Stringa SMILE: [H]C(=O)CCc1ccccc1
• InChI: 1S/C9H10O/c10-8-4-7-9-5-2-1-3-6-9/h1-3,5-6,8H,4,7H2; YGCZTXZTJXYWCO-UHFFFAOYSA-N

Descrizione

Descrizione generale

Hydrocinnamaldehyde is C=C double bond hydrogenated cinnamaldehyde. It has been synthesized by the selective hydrogenation of C=C double bond of cinnamaldehyde by various methods. Hydrocinnamaldehyde and nitromethane undergoes Henry reaction to form nitroaldols. The C1 and C3 position labelled with ¹³C of hydrocinnamaldehyde was subjected to mass spectrometry and the fragmentation pattern was elucidated.

Applicazioni

Hydrocinnamaldehyde may be used in the synthesis of the following:

• 2-Chloro hydrocinnamaldehyde by α-chlorination.
• Mixture of homopropargyl alcohols by kinetic resolution-allenylboration reactions.
• Mixture of syn- and anti-β-hydroxyallylsilanes by hydroboration of allenylsilane.
• (2S)-2-Hydroxy-4-phenylbutanenitrile by catalytic asymmetric cyanosilylation.
• Cinnamaldehyde by dehydrogenation reaction using Pd(TFA)₂/4,5-diazafluorenone catalyst.

Informazioni sulla sicurezza

• Codice della classe di stoccaggio: 10 - Combustible liquids
• Classe di pericolosità dell'acqua (WGK): WGK 2
• Punto d’infiammabilità (°F): 203.0 °F - closed cup
• Punto d’infiammabilità (°C): 95 °C - closed cup
• Dispositivi di protezione individuale: Eyeshields, Gloves, type ABEK (EN14387) respirator filter