396222
1-Chloro-4-iodobutane
98%
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About This Item
Prodotti consigliati
Livello qualitativo
Saggio
98%
Stato
liquid
contiene
copper as stabilizer
Indice di rifrazione
n20/D 1.54 (lit.)
P. ebollizione
88-89 °C/19 mmHg (lit.)
Densità
1.785 g/mL at 25 °C (lit.)
Gruppo funzionale
chloro
iodo
Stringa SMILE
ClCCCCI
InChI
1S/C4H8ClI/c5-3-1-2-4-6/h1-4H2
JXOSPTBRSOYXGC-UHFFFAOYSA-N
Categorie correlate
Descrizione generale
1-Chloro-4-iodobutane is a halogenated hydrocarbon. It is an α,ω-dihaloalkane and undergoes electrogenerated Nickel(I) salen (N,N′-bis(salicylidene)ethylenediamine) catalyzed reduction to afford 1,8-dichlorooctane. Electrochemical reduction of 1-chloro-4-iodobutane at glassy carbon cathode has been investigated by cyclic voltammetry and controlled-potential electrolysis.
Applicazioni
1-Chloro-4-iodobutane may be used in the following studies:
- Preparation of 6-hendecenoic acid.
- Catalytic asymmetric synthesis of levobupivacaine.
- Synthesis of alkaloids such as deoxyvasicinone, mackinazolinone.
Avvertenze
Warning
Indicazioni di pericolo
Consigli di prudenza
Classi di pericolo
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Organi bersaglio
Respiratory system
Codice della classe di stoccaggio
10 - Combustible liquids
Classe di pericolosità dell'acqua (WGK)
WGK 3
Punto d’infiammabilità (°F)
199.4 °F - closed cup
Punto d’infiammabilità (°C)
93 °C - closed cup
Dispositivi di protezione individuale
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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Studies directed towards asymmetric synthesis of levobupivacaine.
Tetrahedron Letters, 46(1), 19-21 (2005)
The synthesis of unsaturated fatty acids.
Journal of the American Chemical Society, 70(5), 1699-1699 (1948-05-01)
Organic & biomolecular chemistry, 5(1), 103-113 (2006-12-14)
Alkyl, aryl, heteroaryl and acyl radicals have been cyclised onto the 2-position of 3H-quinazolin-4-one. The side chains containing the radical precursors were attached to the nitrogen atom in the 3-position. The cyclisations take place by aromatic homolytic substitution hence retain
Electrochemical reduction of 1, 4-dihalobutanes at carbon cathodes in dimethylformamide.
Journal of Electroanalytical Chemistry, 380(1), 147-160 (1995)
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